A supplementary material to the paper Investigation of the B^1\Pi state in NaCs by polarisation labelling spectroscopy Authors: A.Grochola, P.Kowalczyk (c), W.Jastrzebski (c) Corresponding author: e-mail address pfkowal@fuw.edu.pl ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Table 1. Experimental energies of rovibrational levels in the B^1\Pi state (Eexp) and the corresponding values calculated from the IPA potential (Ecalc), in cm-1. Diff are the differences Eexp-Ecalc. In the fit of the potential energy curve of the B^1\Pi state only the levels with flag=1 were used. N v J Eexp Ecalc Diff flag ========================================================= 1 20 13 16226.62097 16227.06160 -.44063 1 2 21 13 16255.75097 16256.15422 -.40325 1 3 22 13 16283.85097 16284.12611 -.27514 1 4 23 13 16310.88097 16310.96982 -.08885 1 5 24 13 16336.72097 16336.69202 .02895 1 6 25 13 16361.43097 16361.29813 .13284 1 7 26 13 16384.97097 16384.76848 .20249 1 8 27 13 16407.15097 16407.03879 .11218 1 9 28 13 16428.19097 16428.01464 .17633 1 10 29 13 16448.10097 16447.67129 .42968 1 11 30 13 16466.92097 16466.16387 .75710 6 12 31 13 16484.88097 16483.75447 1.12650 6 13 33 13 16516.43097 16516.69161 -.26064 1 14 34 13 16532.27097 16532.03834 .23263 1 15 20 15 16228.26295 16228.71203 -.44908 1 16 21 15 16257.43295 16257.76480 -.33185 1 17 22 15 16285.45295 16285.69664 -.24369 1 18 23 15 16312.36295 16312.50032 -.13737 1 19 24 15 16338.21295 16338.18261 .03034 1 20 25 15 16362.87295 16362.74859 .12436 1 21 26 15 16386.31295 16386.17767 .13528 1 22 27 15 16408.48295 16408.40429 .07866 1 23 28 15 16429.43295 16429.33393 .09902 1 24 29 15 16449.34295 16448.94492 .39803 1 25 30 15 16468.18295 16467.39733 .78562 6 26 31 15 16486.11295 16484.95329 1.15966 6 27 33 15 16517.57857 16517.82415 -.24558 1 28 34 15 16533.30857 16533.13669 .17188 1 29 35 15 16547.81857 16547.66005 .15852 1 30 36 15 16561.41857 16561.32643 .09214 1 31 37 15 16574.27857 16574.10984 .16873 1 32 38 15 16586.41857 16586.04472 .37385 1 33 39 15 16597.08857 16597.20682 -.11825 1 34 40 15 16607.84857 16607.68188 .16669 1 35 41 15 16617.65857 16617.51159 .14698 1 36 42 15 16626.74857 16626.66372 .08485 1 37 43 15 16635.09857 16635.08071 .01786 1 38 18 16 16167.85470 16168.26501 -.41031 1 39 19 16 16198.95470 16199.48798 -.53328 6 40 20 16 16229.18470 16229.62230 -.43760 1 41 21 16 16258.32470 16258.65307 -.32837 1 42 22 16 16286.33470 16286.56281 -.22811 1 43 26 16 16387.08470 16386.95474 .12996 1 44 27 16 16409.19470 16409.15722 .03748 1 45 28 16 16430.14470 16430.06132 .08338 1 46 29 16 16450.04470 16449.64713 .39757 1 47 30 16 16468.86470 16468.07743 .78727 6 48 34 16 16533.94470 16533.74221 .20249 1 49 35 16 16548.40470 16548.24551 .15919 1 50 36 16 16561.99470 16561.89062 .10408 1 51 1 19 15466.41609 15466.39597 .02012 1 52 2 19 15518.21609 15518.15207 .06402 1 53 3 19 15568.65609 15568.62720 .02889 1 54 4 19 15617.87609 15617.86334 .01275 1 55 5 19 15665.68609 15665.82106 -.13497 1 56 6 19 15712.03609 15712.34897 -.31288 1 57 7 19 15757.13609 15757.36434 -.22825 1 58 8 19 15800.71609 15800.92424 -.20815 1 59 9 19 15843.13609 15843.13611 -.00002 1 60 10 19 15884.03609 15884.06997 -.03388 1 61 11 19 15923.76609 15923.80546 -.03937 1 62 12 19 15962.35609 15962.38889 -.03280 1 63 13 19 15999.77609 15999.86672 -.09063 1 64 14 19 16036.21609 16036.27753 -.06144 1 65 15 19 16070.29609 16071.64583 -1.34974 6 66 16 19 16105.79609 16105.97636 -.18027 1 67 17 19 16139.04609 16139.25963 -.21354 1 68 18 19 16171.20609 16171.48375 -.27766 1 69 21 19 16261.30800 16261.64932 -.34132 1 70 22 19 16289.27800 16289.48438 -.20638 1 71 23 19 16316.13800 16316.19134 -.05334 1 72 24 19 16341.82800 16341.77718 .05082 1 73 25 19 16366.40800 16366.24609 .16191 1 74 26 19 16389.64800 16389.57523 .07277 1 75 27 19 16411.70800 16411.69597 .01203 1 76 28 19 16432.58800 16432.51370 .07430 1 77 29 19 16452.39800 16452.01458 .38342 1 78 30 19 16471.15800 16470.37054 .78746 6 79 31 19 16489.04800 16487.84319 1.20481 6 80 33 19 16520.39800 16520.55373 -.15573 1 81 34 19 16535.97800 16535.78346 .19454 1 82 35 19 16550.33800 16550.21875 .11925 1 83 36 19 16563.86800 16563.79185 .07615 1 84 37 19 16576.70800 16576.48040 .22760 1 85 38 19 16587.23060 16588.32403 -1.09343 6 86 39 19 16599.34800 16599.39992 -.05192 1 87 40 19 16609.91800 16609.79401 .12399 1 88 41 19 16619.68800 16619.54107 .14693 1 89 42 19 16628.70800 16628.60390 .10410 1 90 43 19 16637.04800 16636.92363 .12437 1 91 0 20 15415.01498 15415.13964 -.12466 1 92 1 20 15468.02498 15468.12429 -.09931 1 93 17 20 16140.27498 16140.47875 -.20377 1 94 18 20 16172.37498 16172.67529 -.30031 1 95 19 20 16203.48498 16203.79662 -.31164 1 96 20 20 16233.49498 16233.82948 -.33450 1 97 21 20 16262.50498 16262.75838 -.25340 1 98 22 20 16290.37498 16290.56577 -.19079 1 99 23 20 16317.20498 16317.24506 -.04008 1 100 24 20 16342.89498 16342.80331 .09167 1 101 25 20 16367.35498 16367.24443 .11055 1 102 26 20 16390.59498 16390.54494 .05004 1 103 27 20 16412.63498 16412.63530 -.00032 1 104 28 20 16433.50498 16433.42097 .08401 1 105 29 20 16453.23498 16452.89043 .34455 1 106 30 20 16471.99498 16471.21895 .77603 6 107 31 20 16489.85498 16488.66787 1.18711 6 108 33 20 16521.22498 16521.33253 -.10755 1 109 34 20 16536.67498 16536.53852 .13646 1 110 35 20 16551.05498 16550.94851 .10647 1 111 36 20 16564.58498 16564.49486 .09012 1 112 37 20 16577.29498 16577.15628 .13870 1 113 40 20 16610.51498 16610.39608 .11890 1 114 41 20 16620.31498 16620.11939 .19559 1 115 42 20 16629.31498 16629.15650 .15848 1 116 43 20 16637.50498 16637.44822 .05676 1 117 45 20 16651.92498 16651.76480 .16018 1 118 46 20 16658.13498 16657.97895 .15603 1 119 47 20 16663.68498 16663.61792 .06706 1 120 48 20 16668.62498 16668.56994 .05504 1 121 49 20 16672.81498 16672.77183 .04315 1 122 50 20 16676.45498 16676.32371 .13127 1 123 2 21 15521.64780 15521.64436 .00344 1 124 3 21 15572.06780 15572.06345 .00435 1 125 4 21 15621.21780 15621.23794 -.02014 1 126 5 21 15669.02780 15669.12719 -.09939 1 127 6 21 15715.61780 15715.58027 .03753 1 128 7 21 15760.51780 15760.51770 .00010 1 129 8 21 15803.98780 15804.00065 -.01285 1 130 9 21 15846.25780 15846.13767 .12013 1 131 10 21 15886.98059 15886.99979 -.01920 1 132 11 21 15926.66059 15926.66674 -.00615 1 133 12 21 15965.22059 15965.18450 .03609 1 134 13 21 16002.40059 16002.59944 -.19885 1 135 16 21 16108.31059 16108.53217 -.22158 1 136 17 21 16141.56059 16141.75849 -.19790 1 137 18 21 16173.65059 16173.92605 -.27546 1 138 19 21 16204.79059 16205.01852 -.22793 1 139 20 21 16234.80059 16235.02256 -.22197 1 140 21 21 16263.71059 16263.92251 -.21192 1 141 22 21 16291.57059 16291.70081 -.13022 1 142 23 21 16318.32059 16318.35105 -.03046 1 143 24 21 16344.00059 16343.88032 .12027 1 144 25 21 16368.38059 16368.29225 .08834 1 145 26 21 16391.66059 16391.56265 .09794 1 146 27 21 16413.64059 16413.62106 .01953 1 147 28 21 16434.46059 16434.37301 .08758 1 148 29 21 16454.15059 16453.80950 .34109 1 149 30 21 16472.85059 16472.10930 .74129 6 150 31 21 16490.70059 16489.53330 1.16729 6 151 33 21 16522.05059 16522.14975 -.09916 1 152 34 21 16537.47059 16537.33079 .13980 1 153 35 21 16551.79059 16551.71415 .07644 1 154 36 21 16565.27059 16565.23236 .03823 1 155 37 21 16578.04059 16577.86526 .17533 1 156 38 21 16588.70059 16589.65548 -.95489 6 157 39 21 16600.63059 16600.68097 -.05038 1 158 40 21 16611.13059 16611.02758 .10301 1 159 41 21 16620.86059 16620.72588 .13471 1 160 42 21 16629.81059 16629.73589 .07470 1 161 43 21 16638.07059 16637.99808 .07251 1 162 44 21 16645.27059 16645.47967 -.20908 1 163 45 21 16652.40059 16652.25730 .14329 1 164 46 21 16658.59059 16658.44615 .14444 1 165 47 21 16664.09059 16664.05678 .03381 1 166 8 22 15805.65714 15805.65086 .00628 1 167 9 22 15847.76714 15847.74773 .01941 1 168 10 22 15888.61714 15888.57138 .04576 1 169 11 22 15928.22714 15928.20155 .02559 1 170 12 22 15966.67714 15966.68407 -.00693 1 171 13 22 16004.32714 16004.06528 .26186 1 172 17 22 16142.91714 16143.09881 -.18167 1 173 0 23 15420.91105 15420.91184 -.00079 1 174 1 23 15473.81105 15473.82502 -.01397 1 175 2 23 15525.48105 15525.47550 .00555 1 176 3 23 15575.86105 15575.83310 .02795 1 177 4 23 15624.93105 15624.93997 -.00892 1 178 5 23 15672.61105 15672.75409 -.14304 1 179 6 23 15719.03105 15719.12510 -.09405 1 180 7 23 15763.92105 15763.97706 -.05601 1 181 8 23 15807.46105 15807.37566 .08539 1 182 9 23 15849.53105 15849.43058 .10047 1 183 10 23 15890.32105 15890.21401 .10704 1 184 11 23 15929.84105 15929.80574 .03531 1 185 12 23 15968.26105 15968.25144 .00961 1 186 13 23 16005.71105 16005.59737 .11368 1 187 14 23 16041.92105 16041.88133 .03972 1 188 15 23 16077.03105 16077.12629 -.09524 1 189 16 23 16111.30105 16111.33585 -.03480 1 190 17 23 16144.36105 16144.49964 -.13859 1 191 18 23 16176.40105 16176.60508 -.20403 1 192 21 23 16266.20284 16266.41575 -.21291 1 193 22 23 16294.00284 16294.13169 -.12885 1 194 23 23 16320.70284 16320.71960 -.01676 1 195 24 23 16346.30284 16346.18671 .11613 1 196 25 23 16370.62284 16370.53599 .08685 1 197 26 23 16393.79284 16393.74174 .05110 1 198 27 23 16415.69284 16415.73148 -.03864 1 199 28 23 16436.46284 16436.41106 .05178 1 200 29 23 16456.11284 16455.77697 .33587 1 201 30 23 16474.81284 16474.01547 .79737 6 202 31 23 16492.59284 16491.38620 1.20664 6 203 33 23 16523.82284 16523.89916 -.07632 1 204 34 23 16539.14284 16539.02658 .11626 1 205 35 23 16553.43284 16553.35265 .08019 1 206 36 23 16566.87284 16566.81041 .06243 1 207 37 23 16579.54284 16579.38213 .16071 1 208 38 23 16590.32284 16591.11372 -.79088 6 209 39 23 16602.08284 16602.08402 -.00118 1 210 40 23 16612.50284 16612.37847 .12437 1 211 41 23 16622.10284 16622.02291 .07993 1 212 42 23 16631.02284 16630.97450 .04834 1 213 43 23 16639.24284 16639.17308 .06976 1 214 44 23 16646.45284 16646.59001 -.13717 1 215 7 24 15765.75692 15765.82135 -.06443 1 216 8 24 15809.21692 15809.17500 .04192 1 217 9 24 15851.18692 15851.18616 .00076 1 218 10 24 15892.02692 15891.92764 .09928 1 219 11 24 15931.46692 15931.47926 -.01234 1 220 12 24 15969.93692 15969.88653 .05039 1 221 17 24 16145.80692 16145.96094 -.15402 1 222 18 24 16177.83692 16178.03322 -.19630 1 223 19 24 16208.74692 16209.03076 -.28384 1 224 20 24 16238.74692 16238.93999 -.19307 1 225 21 24 16267.54692 16267.74473 -.19781 1 226 22 24 16295.35692 16295.42738 -.07046 1 227 23 24 16322.01692 16321.98203 .03489 1 228 24 24 16347.53692 16347.41596 .12096 1 229 25 24 16371.82692 16371.73179 .09513 1 230 26 24 16394.97692 16394.90297 .07395 1 231 27 24 16416.84692 16416.85598 -.00906 1 232 28 24 16437.59692 16437.49688 .10004 1 233 29 24 16457.16692 16456.82519 .34173 1 234 30 24 16475.83692 16475.03111 .80581 6 235 31 24 16493.60692 16492.37348 1.23344 6 236 33 24 16524.76692 16524.83117 -.06425 1 237 34 24 16540.04692 16539.92993 .11699 1 238 35 24 16554.33692 16554.22531 .11161 1 239 36 24 16567.67692 16567.65074 .02618 1 240 37 24 16580.34692 16580.18981 .15711 1 241 38 24 16591.26692 16591.89015 -.62323 6 242 39 24 16602.86692 16602.83104 .03588 1 243 40 24 16613.27692 16613.09763 .17929 1 244 41 24 16622.78692 16622.71322 .07370 1 245 42 24 16631.69692 16631.63345 .06347 1 246 43 24 16639.90692 16639.79789 .10903 1 247 44 24 16647.06692 16647.18034 -.11342 1 248 45 24 16654.07692 16653.86900 .20792 1 249 46 24 16660.08692 16659.97432 .11260 1 250 47 24 16665.50692 16665.48997 .01695 1 251 48 24 16670.34692 16670.29365 .05327 1 252 49 24 16674.34692 16674.34459 .00233 1 253 50 24 16677.85692 16677.75979 .09713 1 254 1 26 15480.32060 15480.29806 .02254 1 255 2 26 15531.90060 15531.85637 .04423 1 256 3 26 15582.14060 15582.11156 .02904 1 257 4 26 15631.07060 15631.10584 -.03524 1 258 5 26 15678.74060 15678.79481 -.05421 1 259 6 26 15725.01060 15725.02913 -.01853 1 260 7 26 15769.74060 15769.73885 .00175 1 261 8 26 15813.22060 15812.99707 .22353 1 262 9 26 15855.10060 15854.91529 .18531 1 263 10 26 15895.66060 15895.56767 .09293 1 264 11 26 15935.11060 15935.03408 .07652 1 265 12 26 15973.36060 15973.35971 .00089 1 266 13 26 16010.68060 16010.59062 .08998 1 267 14 26 16046.76060 16046.76395 -.00335 1 268 15 26 16081.63060 16081.90128 -.27068 1 269 16 26 16115.88060 16116.00525 -.12465 1 270 17 26 16148.91060 16149.06472 -.15412 1 271 25 26 16374.40396 16374.27082 .13314 1 272 26 26 16397.37396 16397.36836 .00560 1 273 27 26 16419.22396 16419.24306 -.01910 1 274 28 26 16439.82396 16439.80159 .02237 1 275 29 26 16459.36396 16459.05012 .31384 1 276 30 26 16478.01396 16477.18713 .82683 6 277 31 26 16495.74396 16494.46933 1.27463 6 278 33 26 16526.74396 16526.80938 -.06542 1 279 34 26 16541.92396 16541.84703 .07693 1 280 35 26 16556.14396 16556.07691 .06705 1 281 36 26 16569.47396 16569.43344 .04052 1 282 37 26 16582.09396 16581.90305 .19091 1 283 39 26 16604.38396 16604.41551 -.03155 1 284 40 26 16614.72396 16614.62282 .10114 1 285 41 26 16624.22396 16624.17674 .04722 1 286 42 26 16633.08396 16633.02988 .05408 1 287 43 26 16641.21396 16641.12132 .09264 1 288 44 26 16648.39396 16648.43055 -.03659 1 289 45 26 16655.15396 16655.05381 .10015 1 290 46 26 16661.20396 16661.09690 .10706 1 291 47 26 16666.56396 16666.54036 .02360 1 292 48 26 16671.21396 16671.25791 -.04395 1 293 49 26 16675.24396 16675.22341 .02055 1 294 50 26 16678.66396 16678.56018 .10378 1 295 1 28 15485.09619 15485.04152 .05467 1 296 2 28 15536.58619 15536.53222 .05397 1 297 3 28 15586.70619 15586.71234 -.00615 1 298 4 28 15635.63619 15635.62413 .01206 1 299 5 28 15683.17619 15683.22138 -.04519 1 300 6 28 15729.35619 15729.35555 .00064 1 301 7 28 15774.13619 15773.96110 .17509 1 302 8 28 15817.25619 15817.11654 .13965 1 303 9 28 15859.06619 15858.93463 .13156 1 304 10 28 15899.55619 15899.49101 .06518 1 305 11 28 15938.90619 15938.86555 .04064 1 306 13 28 16014.35619 16014.24972 .10647 1 307 14 28 16050.25619 16050.34192 -.08573 1 308 15 28 16085.47619 16085.40029 .07590 1 309 16 28 16119.43619 16119.42675 .00944 1 310 17 28 16152.28619 16152.40964 -.12345 1 311 18 28 16184.18619 16184.33532 -.14913 1 312 21 28 16273.51728 16273.60821 -.09093 1 313 22 28 16301.09728 16301.14358 -.04630 1 314 23 28 16327.54728 16327.55111 -.00383 1 315 24 28 16352.92728 16352.83823 .08905 1 316 25 28 16377.06728 16377.00588 .06140 1 317 26 28 16400.02728 16400.02373 .00355 1 318 27 28 16421.73728 16421.81359 -.07631 1 319 28 28 16442.25728 16442.28302 -.02574 1 320 29 28 16461.80728 16461.44569 .36159 1 321 30 28 16480.34728 16479.50885 .83843 6 322 31 28 16498.07728 16496.72630 1.35098 6 323 33 28 16528.91728 16528.93918 -.02190 1 324 34 28 16543.96728 16543.91065 .05663 1 325 35 28 16558.06728 16558.06945 -.00217 1 326 36 28 16571.38728 16571.35135 .03593 1 327 38 28 16594.84728 16595.30836 -.46108 1 328 39 28 16606.10728 16606.11975 -.01247 1 329 40 28 16616.37728 16616.26296 .11432 1 330 41 28 16625.82728 16625.74984 .07744 1 331 42 28 16634.57728 16634.52991 .04737 1 332 44 28 16649.73728 16649.77233 -.03505 1 333 45 28 16656.41728 16656.32537 .09191 1 334 46 28 16662.40728 16662.30073 .10655 1 335 47 28 16667.65728 16667.66435 -.00707 1 336 0 29 15434.86100 15434.80077 .06023 1 337 1 29 15487.59100 15487.54145 .04955 1 338 2 29 15538.98100 15538.99648 -.01548 1 339 3 29 15589.23100 15589.13704 .09396 1 340 8 29 15819.37100 15819.28765 .08335 1 341 9 29 15861.17100 15861.05297 .11803 1 342 10 29 15901.62100 15901.55877 .06223 1 343 11 29 15940.89100 15940.88488 .00612 1 344 12 29 15979.22100 15979.07609 .14491 1 345 18 29 16185.97100 16186.05789 -.08689 1 346 19 29 16216.78100 16216.86933 -.08833 1 347 20 29 16246.49100 16246.59265 -.10165 1 348 21 29 16275.15100 16275.21060 -.05960 1 349 22 29 16302.71100 16302.70561 .00539 1 350 23 29 16329.13100 16329.07283 .05817 1 351 24 29 16354.42100 16354.31971 .10129 1 352 25 29 16378.56100 16378.44670 .11430 1 353 26 29 16401.35100 16401.42241 -.07141 1 354 27 29 16423.09100 16423.16736 -.07636 1 355 28 29 16443.63100 16443.58971 .04129 1 356 29 29 16463.00100 16462.70721 .29379 1 357 30 29 16481.58100 16480.73160 .84940 6 358 31 29 16499.29100 16497.91501 1.37599 6 359 33 29 16530.01100 16530.06067 -.04967 1 360 34 29 16545.06100 16544.99712 .06388 1 361 35 29 16559.11100 16559.11826 -.00726 1 362 36 29 16572.40100 16572.36068 .04032 1 363 40 29 16617.12100 16617.12580 -.00480 1 364 42 29 16635.40100 16635.31832 .08268 1 365 44 29 16650.48100 16650.47710 .00390 1 366 45 29 16657.10100 16656.99323 .10777 1 367 46 29 16663.07100 16662.93257 .13843 1 368 47 29 16668.29100 16668.25322 .03778 1 369 48 29 16672.81100 16672.82590 -.01490 1 370 50 29 16679.96100 16679.85633 .10467 1 371 51 29 16682.56100 16682.47261 .08839 1 372 52 29 16684.66100 16684.52980 .13120 1 373 1 31 15492.78233 15492.79728 -.01495 1 374 2 31 15544.13233 15544.17726 -.04493 1 375 3 31 15594.25233 15594.23463 .01770 1 376 4 31 15642.99233 15643.01155 -.01922 1 377 5 31 15690.56233 15690.45878 .10355 1 378 6 31 15736.44233 15736.42923 .01310 1 379 7 31 15780.92233 15780.86466 .05767 1 380 8 31 15824.08233 15823.85224 .23009 1 381 9 31 15865.61233 15865.50667 .10566 1 382 10 31 15905.97233 15905.90613 .06620 1 383 11 31 15945.13233 15945.13040 .00193 1 384 12 31 15983.40233 15983.22402 .17831 1 385 13 31 16020.43233 16020.23258 .19975 1 386 14 31 16056.34233 16056.19196 .15037 1 387 15 31 16091.21233 16091.12105 .09128 1 388 16 31 16125.09233 16125.02058 .07175 1 389 17 31 16157.93233 16157.87803 .05430 1 390 18 31 16189.63233 16189.67901 -.04668 1 391 21 31 16278.56134 16278.57866 -.01732 1 392 22 31 16305.98134 16305.98868 -.00734 1 393 23 31 16332.34134 16332.27101 .07033 1 394 24 31 16357.51134 16357.43315 .07819 1 395 25 31 16381.52134 16381.47446 .04688 1 396 26 31 16404.30134 16404.36122 -.05988 1 397 27 31 16425.88134 16426.01133 -.12999 1 398 28 31 16446.30134 16446.33442 -.03308 1 399 29 31 16465.75134 16465.35712 .39422 1 400 30 31 16484.15134 16483.30043 .85091 6 401 31 31 16501.94134 16500.41226 1.52908 6 402 32 31 16516.11134 16516.78599 -.67465 6 403 33 31 16532.39134 16532.41628 -.02494 1 404 34 31 16547.35134 16547.27877 .07257 1 405 35 31 16561.33134 16561.32027 .01107 1 406 36 31 16574.51134 16574.47936 .03198 1 407 37 31 16587.06134 16586.75115 .31019 1 408 38 31 16597.81134 16598.19650 -.38516 1 409 39 31 16608.87134 16608.89838 -.02704 1 410 40 31 16619.04134 16618.93627 .10507 1 411 41 31 16628.34134 16628.31214 .02920 1 412 43 31 16644.50134 16644.85159 -.35025 1 413 44 31 16652.01134 16651.95342 .05792 1 414 45 31 16658.47134 16658.39216 .07918 1 415 17 32 16159.81442 16159.82081 -.00639 1 416 18 32 16191.55442 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4 51 15710.85223 15710.77225 .07998 1 876 4 51 15710.79103 15710.77225 .01878 1 877 5 51 15756.42223 15756.83840 -.41617 1 878 5 51 15756.43103 15756.83840 -.40737 1 879 6 51 15799.64223 15801.30784 -1.66561 6 880 11 51 16000.31103 16002.61914 -2.30811 6 881 12 51 16037.62103 16039.38843 -1.76740 6 882 13 51 16074.03103 16075.12543 -1.09440 6 883 15 51 16143.15103 16143.59042 -.43939 1 884 16 51 16176.12103 16176.31179 -.19076 1 885 17 51 16207.93103 16208.00377 -.07274 1 886 18 51 16238.68103 16238.64463 .03640 1 887 19 51 16268.25103 16268.21481 .03622 1 888 21 51 16324.07103 16324.06322 .00781 1 889 22 51 16350.14103 16350.30375 -.16272 1 890 23 51 16375.20103 16375.41875 -.21772 1 891 24 51 16398.96103 16399.41150 -.45047 1 892 25 51 16421.58103 16422.25967 -.67864 6 893 26 51 16443.15103 16443.89170 -.74067 6 894 27 51 16463.59103 16464.19999 -.60896 6 895 28 51 16483.05103 16483.15491 -.10388 1 896 29 51 16496.84103 16500.93450 -4.09347 6 897 30 51 16515.71103 16517.82549 -2.11446 6 898 31 51 16532.80103 16533.96769 -1.16666 6 899 32 51 16548.62103 16549.36699 -.74596 6 900 33 51 16563.42103 16563.99363 -.57260 6 901 34 51 16577.40103 16577.79735 -.39632 1 902 36 51 16601.38103 16602.69518 -1.31415 6 903 37 51 16612.92103 16613.83487 -.91384 6 904 38 51 16623.60103 16624.21202 -.61099 6 905 39 51 16633.52103 16633.91010 -.38907 1 906 40 51 16641.48103 16642.92350 -1.44247 6 907 41 51 16650.35103 16651.18218 -.83115 6 908 42 51 16657.94103 16658.61482 -.67379 6 909 43 51 16664.72103 16665.24250 -.52147 6 910 44 51 16670.82103 16671.20689 -.38586 1 911 45 51 16675.75103 16676.55410 -.80307 6 912 46 51 16680.49103 16681.13659 -.64556 6 913 47 51 16684.28103 16684.83380 -.55277 6 914 48 51 16687.98103 16687.76421 .21682 1 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Table 2. Parameters defining the IPA potential energy curve for the B^1\Pi state of NaCs. R[A] U[cm-1] 3.4 28303.3752 3.6 19755.5597 3.7 17921.4827 3.8 16463.3209 3.9 15787.6419 4.0 15580.2126 4.2 15417.0134 4.4 15370.0231 4.6 15394.9854 4.8 15463.8153 5.2 15649.2462 5.6 15824.2158 6.0 15981.0697 6.4 16121.4339 6.8 16239.3309 7.2 16332.8827 7.6 16404.7489 8.0 16456.2907 8.8 16538.1047 9.6 16589.8797 10.0 16624.5842 11.2 16645.6826 12.0 16660.1290 12.8 16668.6771 14.4 16677.7711 16.0 16682.0108 17.6 16684.0715 19.2 16685.1259 20.8 16685.6952 22.4 16686.0165 24.8 16686.2696 R_out = 13.18506 A U_inf = 16686.547 cm-1 C_6 = 5.16831E+07 cm-1 A^6 C_8 = 9.42143E+09 cm-1 A^8 C_10 = -8.18828E+11 cm-1 A^10