Polarisation labelling spectroscopy of rubidium dimer:
highly excited 81\Sigma+u, 91\Sigma+u and 81\Piu states
W. Jastrzebski, A. Grochola, J. Szczepkowski, P. Kowalczyk

A. Measured line positions in the 81\Piu <-- X1\Sigma+g system of Rb2

Only lines with flags 1 and 2 were used in the final fit
of molecular constants. Asterisks denote lines corresponding
to the 85Rb87Rb isotopologue, otherwise they relate to 85Rb2.

 v' J' v" J" freq. [cm-1] flag
  8 50  1 50 29038.540000   1   
  9 49  1 50 29081.940000   1   
  9 50  1 50 29083.280000   1   
  9 51  1 50 29085.380000   1   
 10 49  1 50 29126.550000   1   
 10 50  1 50 29127.840000   1   
 11 49  1 50 29171.080000   1   
 11 50  1 50 29172.150000   1   
 12 50  1 50 29216.160000   1   
 13 50  1 50 29259.710000   6   
 18 50  1 50 29477.950000   1   
 19 50  1 50 29520.800000   1   
 20 50  1 50 29563.380000   1   
 21 50  1 50 29606.060000   1   
 22 50  1 50 29648.390000   1   
 23 50  1 50 29690.530000   1   
  7 50  1 50 28991.350000 * 6   
  8 50  1 50 29037.010000 * 2   
  9 49  1 50 29080.180000 * 2   
  9 50  1 50 29081.480000 * 2   
  9 51  1 50 29083.470000 * 2   
 10 49  1 50 29124.570000 * 2   
 10 50  1 50 29125.800000 * 2   
 11 49  1 50 29168.900000 * 2   
 11 50  1 50 29169.850000 * 2   
 12 49  1 50 29212.280000 * 6   
 12 50  1 50 29213.630000 * 6   
 12 51  1 50 29215.580000 * 6   
 13 50  1 50 29256.940000 * 6   
 15 50  1 50 29344.920000 * 2   
 16 50  1 50 29388.370000 * 2   
 17 49  1 50 29429.870000 * 2   
 17 50  1 50 29431.590000 * 2   
 18 50  1 50 29474.080000 * 2   
 19 49  1 50 29515.290000 * 2   
 19 50  1 50 29516.650000 * 2   
 19 51  1 50 29518.560000 * 2   
 20 50  1 50 29558.960000 * 2   
 21 50  1 50 29601.460000 * 2   
 22 49  1 50 29642.640000 * 6   
 22 50  1 50 29643.520000 * 2   
 23 49  1 50 29684.170000 * 2   
 23 50  1 50 29685.450000 * 2   
 23 51  1 50 29687.310000 * 2   
  2 50  3 50 28652.650000 * 2   
  3 50  3 50 28698.250000 * 2   
  4 50  3 50 28743.740000 * 2   
  5 50  3 50 28789.030000 * 2   
  6 50  3 50 28834.150000 * 2   
  7 50  3 50 28879.090000 * 2   
 11 54  1 54 29169.760000   1   
 12 54  1 54 29213.650000   6   
 13 54  1 54 29257.090000   6   
  8 54  1 54 29034.590000 * 2   
  9 54  1 54 29079.060000 * 2   
 10 54  1 54 29123.330000 * 2   
 11 54  1 54 29167.400000 * 2   
 12 54  1 54 29211.220000 * 2   
 13 54  1 54 29254.440000 * 6   
  9 54  1 55 29078.750000   1   
  9 55  1 55 29080.220000   1   
  9 56  1 55 29082.450000   1   
 10 55  1 55 29124.720000   1   
 11 54  1 55 29167.830000   1   
 11 55  1 55 29169.070000   1   
 12 55  1 55 29213.040000   1   
 13 55  1 55 29256.530000   6   
  3 55  3 55 28695.060000   1   
  4 55  3 55 28740.750000   1   
  5 55  3 55 28786.320000   1   
  6 55  3 55 28831.360000   1   
  7 55  3 55 28876.580000   1   
  0 63  6 63 28383.730000   6   
  2 63  6 63 28475.660000   1   
  3 63  6 63 28521.520000   1   
  5 63  6 63 28612.670000   1   
  6 63  6 63 28657.920000   1   
 13 66  0 66 29303.920000 * 6   
 14 66  0 66 29347.670000 * 6   
 15 66  0 66 29390.030000 * 6   
  8 66  0 66 29085.020000   1   
  9 65  0 66 29127.850000   1   
  9 66  0 66 29129.750000   1   
 11 65  0 66 29217.130000   1   
 11 66  0 66 29218.460000   1   
 13 66  0 66 29307.560000   6   
 14 65  0 66 29349.460000   6   
 14 66  0 66 29351.050000   6   
 15 65  0 66 29392.840000   1   
 15 66  0 66 29394.590000   1   
 15 67  0 66 29397.130000   1   
 16 66  0 66 29437.860000   1   
 16 67  0 66 29440.300000   1   
 17 66  0 66 29480.900000   1   
 18 65  0 66 29522.410000   1   
 18 66  0 66 29523.720000   1   
 18 67  0 66 29526.300000   1   
 19 65  0 66 29564.760000   1   
 19 66  0 66 29566.610000   1   
 19 67  0 66 29569.060000   1   
 20 66  0 66 29609.380000   1   
 12 66  0 66 29263.940000 * 6   
 13 66  0 66 29303.920000 * 2   
 14 66  0 66 29347.560000 * 2   
 15 66  0 66 29390.050000 * 6   
 16 66  0 66 29434.150000 * 2   
 17 66  0 66 29477.010000 * 2   
 18 66  0 66 29519.710000 * 2   
  9 70  0 70 29126.610000   1   
 10 70  0 70 29171.010000   1   
 11 69  0 70 29213.840000   1   
 11 70  0 70 29215.250000   1   
 12 69  0 70 29257.190000   6   
 12 70  0 70 29259.150000   6   
 12 71  0 70 29261.800000   6   
 13 70  0 70 29302.520000   6   
 14 69  0 70 29346.010000   1   
 14 70  0 70 29347.730000   1   
 14 71  0 70 29350.260000   1   
 15 70  0 70 29391.230000   1   
 16 70  0 70 29434.530000   1   
 17 69  0 70 29475.820000   1   
 17 70  0 70 29477.580000   1   
 18 69  0 70 29518.980000   1   
 18 70  0 70 29520.510000   1   
 18 71  0 70 29523.530000   1   
 19 69  0 70 29561.360000   1   
 19 70  0 70 29563.170000   1   
 19 71  0 70 29565.820000   1   
 20 69  0 70 29604.030000   1   
 20 70  0 70 29605.900000   1   
 21 70  0 70 29648.330000   1   
  9 70  0 70 29124.600000 * 2   
 10 69  0 70 29167.080000 * 2   
 10 70  0 70 29168.950000 * 2   
 11 70  0 70 29212.800000 * 2   
 12 70  0 70 29256.490000 * 6   
 13 70  0 70 29300.320000 * 6   
 14 70  0 70 29344.600000 * 6   
 15 69  0 70 29385.860000 * 2   
 15 70  0 70 29387.660000 * 2   
 16 70  0 70 29430.820000 * 2   
 17 70  0 70 29473.710000 * 2   
 18 69  0 70 29514.890000 * 2   
 18 70  0 70 29516.400000 * 2   
 19 70  0 70 29558.910000 * 2   
 20 70  0 70 29601.440000 * 2   
 21 70  0 70 29643.610000 * 2   
  3 70  4 70 28628.480000   1   
  4 70  4 70 28674.100000   1   
  5 70  4 70 28719.530000   1   
  8 70  4 70 28854.780000   1   
  9 70  4 70 28899.410000   1   
 10 70  4 70 28943.870000   1   
  9 71  1 71 29068.540000   1   
 10 71  1 71 29112.890000   1   
 11 71  1 71 29157.210000   1   
 12 71  1 71 29201.090000   6   
 11 72  0 73 29211.220000   1   
 11 73  0 73 29212.770000   1   
 11 74  0 73 29215.660000   1   
 12 73  0 73 29256.580000   6   
 13 73  0 73 29300.230000   6   
 14 72  0 73 29343.350000   1   
 14 73  0 73 29345.100000   1   
 15 72  0 73 29386.660000   1   
 15 73  0 73 29388.560000   1   
 15 74  0 73 29391.230000   1   
 16 72  0 73 29430.280000   1   
 16 73  0 73 29431.920000   1   
 17 73  0 73 29474.880000   1   
 18 72  0 73 29516.200000   1   
 18 73  0 73 29517.840000   1   
 19 73  0 73 29560.540000   1   
  0 73  8 73 28266.360000   6   
  1 73  8 73 28311.910000   1   
  4 73  8 73 28449.370000   1   
  5 73  8 73 28494.730000   1   
  8 79  0 79 29074.230000   1   
  9 79  0 79 29118.470000   1   
 10 79  0 79 29163.420000   1   
 11 79  0 79 29207.320000   1   
 12 78  0 79 29249.270000   6   
 12 79  0 79 29251.160000   6   
 13 79  0 79 29294.390000   6   
 14 79  0 79 29339.650000   1   
 15 79  0 79 29383.490000   6   
 16 79  0 79 29426.320000   1   
 17 78  0 79 29467.460000   1   
 17 79  0 79 29469.380000   1   
 17 80  0 79 29472.590000   1   
 18 78  0 79 29510.500000   1   
 18 79  0 79 29512.210000   1   
 18 80  0 79 29515.490000   1   
 19 78  0 79 29553.330000   1   
 19 79  0 79 29554.930000   1   
 19 80  0 79 29558.070000   1   
 20 79  0 79 29597.580000   1   
 21 79  0 79 29639.920000   1   
  0 79  6 79 28372.000000   1   
  1 79  6 79 28417.800000   6   
  2 79  6 79 28463.890000   1   
  3 79  6 79 28509.570000   1   
  5 79  6 79 28600.590000   1   
  6 79  6 79 28645.810000   1   
  7 79  6 79 28690.840000   1   
  9 80  0 80 29117.840000   1   
 10 80  0 80 29162.390000   1   
 11 80  0 80 29206.370000   6   
 12 80  0 80 29250.210000   6   
 14 79  0 80 29336.540000   1   
 14 80  0 80 29338.650000   1   
 15 79  0 80 29380.150000   1   
 15 80  0 80 29382.450000   6   
 15 81  0 80 29385.370000   1   
 16 80  0 80 29425.360000   1   
 17 80  0 80 29468.370000   1   
 18 79  0 80 29509.450000   1   
 18 80  0 80 29511.230000   1   
 18 81  0 80 29514.700000   1   
 19 80  0 80 29553.880000   1   
 20 80  0 80 29596.500000   1   
  9 80  0 80 29116.000000 * 2   
 10 80  0 80 29160.210000 * 2   
 11 79  0 80 29202.470000 * 2   
 11 80  0 80 29204.050000 * 2   
 12 80  0 80 29247.640000 * 6   
 14 79  0 80 29333.440000 * 2   
 14 80  0 80 29335.590000 * 2   
 15 79  0 80 29376.860000 * 2   
 15 80  0 80 29379.050000 * 6   
 15 81  0 80 29382.040000 * 2   
 16 79  0 80 29419.930000 * 2   
 16 80  0 80 29421.910000 * 2   
 16 81  0 80 29424.940000 * 2   
 17 80  0 80 29464.650000 * 2   
 18 79  0 80 29505.520000 * 2   
 18 80  0 80 29507.280000 * 2   
 19 79  0 80 29548.060000 * 2   
 19 80  0 80 29549.720000 * 2   
  7 81  1 81 28970.400000   1   
  8 81  1 81 29015.180000   1   
  9 80  1 81 29057.930000   1   
  9 81  1 81 29059.760000   1   
 10 81  1 81 29104.300000   1   
 11 81  1 81 29148.310000   1   
 12 81  1 81 29192.110000   6   
 13 81  1 81 29235.310000   6   
 14 81  1 81 29280.510000   1   
 16 81  1 81 29367.020000   1   
 17 81  1 81 29410.260000   1   
 18 80  1 81 29451.320000   1   
 18 81  1 81 29453.140000   1   
 19 81  1 81 29495.750000   1   
 20 81  1 81 29538.340000   1   
 21 80  1 81 29578.720000   1   
 21 81  1 81 29580.750000   1   
 22 80  1 81 29621.260000   1   
 22 81  1 81 29622.880000   1   
 23 81  1 81 29664.790000   1   
 24 81  1 81 29706.180000   1   
  7 81  1 81 28969.420000 * 2   
  8 81  1 81 29013.940000 * 2   
  9 81  1 81 29058.270000 * 2   
 10 81  1 81 29102.510000 * 2   
 11 81  1 81 29146.310000 * 2   
 12 81  1 81 29189.920000 * 6   
 13 81  1 81 29232.860000 * 6   
 14 81  1 81 29277.820000 * 2   
 15 81  1 81 29321.030000 * 2   
 16 81  1 81 29363.400000 * 6   
 18 81  1 81 29449.470000 * 2   
 19 81  1 81 29491.930000 * 2   
 20 81  1 81 29534.510000 * 2   
 21 81  1 81 29576.450000 * 2   
 22 81  1 81 29618.350000 * 2   
 23 81  1 81 29660.130000 * 2   
 24 81  1 81 29701.540000 * 2   
  0 83  8 83 28258.090000   1   
  1 83  8 83 28304.210000   1   
  3 83  8 83 28395.720000   1   
  4 83  8 83 28441.330000   1   
  8 83  8 83 28621.640000   1   
  9 83  8 83 28666.300000   1   
 12 83  8 83 28798.590000   1   
 13 83  8 83 28843.150000   1   
 14 83  8 83 28886.730000   1   
  1 85  4 85 28524.940000   6   
  2 85  4 85 28570.310000   1   
  3 85  4 85 28616.000000   1   
  4 85  4 85 28661.590000   1   
  5 85  4 85 28706.880000   1   
  8 85  4 85 28841.850000   1   
  9 85  4 85 28886.470000   1   
 10 85  4 85 28930.870000   1   
  9 86  0 86 29112.040000   1   
 10 86  0 86 29156.460000   1   
 11 85  0 86 29198.810000   1   
 11 86  0 86 29200.530000   1   
 12 86  0 86 29244.290000   6   
 14 86  0 86 29332.500000   1   
 15 85  0 86 29374.100000   1   
 15 86  0 86 29376.320000   6   
 15 87  0 86 29379.360000   1   
 16 86  0 86 29419.290000   1   
 17 86  0 86 29462.240000   1   
 18 85  0 86 29503.160000   1   
 18 86  0 86 29505.060000   1   
 19 86  0 86 29547.660000   1   
 19 87  0 86 29551.450000   1   
 20 86  0 86 29590.850000   6   
 10 86  0 86 29154.470000 * 2   
 11 86  0 86 29198.280000 * 2   
 12 86  0 86 29241.800000 * 6   
 13 86  0 86 29284.720000 * 6   
 14 86  0 86 29329.590000 * 2   
 15 86  0 86 29373.070000 * 6   
 16 86  0 86 29415.890000 * 2   
 17 86  0 86 29458.640000 * 2   
 18 86  0 86 29501.210000 * 2   
 19 86  0 86 29543.550000 * 2   
  8 88  1 88 29008.410000   1   
  9 88  1 88 29053.000000   1   
 10 87  1 88 29095.130000   1   
 10 88  1 88 29097.350000   1   
 10 89  1 88 29101.290000   1   
 11 87  1 88 29139.650000   1   
 11 88  1 88 29141.410000   1   
 12 88  1 88 29185.160000   6   
 13 88  1 88 29228.210000   6   
 14 88  1 88 29273.320000   1   
 18 87  1 88 29443.990000   1   
 18 88  1 88 29445.880000   1   
 19 88  1 88 29488.480000   1   
 20 88  1 88 29531.170000   1   
 21 88  1 88 29573.410000   1   
 22 88  1 88 29615.490000   1   
 23 88  1 88 29657.310000   1   
  9 88  1 88 29051.530000 * 2   
 10 88  1 88 29095.660000 * 2   
 11 88  1 88 29139.520000 * 2   
 12 88  1 88 29183.000000 * 6   
  8 89  1 89 29007.440000   1   
  9 89  1 89 29051.960000   1   
 10 89  1 89 29096.300000   1   
 11 88  1 89 29138.590000   1   
 11 89  1 89 29140.360000   1   
 12 89  1 89 29184.130000   6   
 13 89  1 89 29227.200000   6   
 18 89  1 89 29444.840000   1   
 19 89  1 89 29487.370000   1   
 20 89  1 89 29529.810000   1   
 21 89  1 89 29572.290000   1   
 22 88  1 89 29612.530000   1   
 22 89  1 89 29614.420000   1   
 23 89  1 89 29656.270000   1   
 10 90  0 90 29152.310000   1   
 11 90  0 90 29196.340000   1   
 12 90  0 90 29240.140000   6   
 14 90  0 90 29328.190000   1   
 15 89  0 90 29369.920000   1   
 15 90  0 90 29372.070000   6   
 15 91  0 90 29375.150000   6   
 16 90  0 90 29415.100000   1   
 17 90  0 90 29457.990000   1   
 18 89  0 90 29498.790000   1   
 18 90  0 90 29500.750000   1   
 19 90  0 90 29543.310000   1   
 20 90  0 90 29585.990000   1   
  7 91  1 91 28960.070000   6   
  8 90  1 91 29003.250000   1   
  8 91  1 91 29005.370000   1   
  9 90  1 91 29047.730000   1   
  9 91  1 91 29049.900000   1   
 10 91  1 91 29094.260000   1   
 11 90  1 91 29136.460000   1   
 11 91  1 91 29138.280000   1   
 11 92  1 91 29142.430000   1   
 12 91  1 91 29182.000000   6   
 13 91  1 91 29225.050000   6   
 14 91  1 91 29270.080000   1   
 17 91  1 91 29399.850000   1   
 18 90  1 91 29440.610000   1   
 18 91  1 91 29442.630000   1   
 19 91  1 91 29485.140000   1   
 20 91  1 91 29527.820000   1   
 21 91  1 91 29570.080000   1   
 22 91  1 91 29612.140000   1   
 23 91  1 91 29653.910000   1   
  0 92  8 92 28250.320000   1   
  1 92  8 92 28296.180000   1   
  2 92  8 92 28341.940000   1   
  3 92  8 92 28387.650000   1   
  9100  0100 29099.560000   6   
 10100  0100 29141.210000   1   
 11100  0100 29185.180000   1   
 12100  0100 29231.520000   6   
 13100  0100 29267.600000   6   
 14100  0100 29316.670000   1   
 15100  0100 29360.490000   1   
 16100  0100 29403.540000   1   
 17100  0100 29446.430000   1   
 18100  0100 29489.110000   1   
 19100  0100 29531.460000   1   
 20100  0100 29574.180000   1   
  8100  0100 29051.160000 * 2   
  9100  0100 29095.360000 * 2   
 10100  0100 29139.390000 * 2   
 11100  0100 29183.150000 * 2   
 12100  0100 29226.560000 * 6   
 14100  0100 29313.930000 * 2   
 15100  0100 29357.710000 * 6   
 16100  0100 29400.350000 * 2   
 17100  0100 29442.950000 * 2   
 18100  0100 29485.430000 * 2   
 19100  0100 29527.580000 * 2   
 20100  0100 29570.040000 * 2   
 21100  0100 29611.960000 * 2   
  7102  1102 28948.670000   1   
  8102  1102 28993.280000   1   
  9102  1102 29037.690000   1   
 10102  1102 29081.980000   1   
 11102  1102 29125.940000   1   
 12102  1102 29169.600000   6   
 14102  1102 29257.240000   1   
 18102  1102 29429.730000   1   
 19102  1102 29472.030000   1   
 20102  1102 29514.780000   1   
 21102  1102 29556.930000   1   
 22102  1102 29598.960000   1   
 23102  1102 29640.520000   1   
 24102  1102 29682.550000   1   
  8103  0103 29049.040000   1   
  9103  0103 29093.450000   1   
 10103  0103 29137.670000   1   
 11103  0103 29181.640000   1   
 12103  0103 29225.150000   6   
 13103  0103 29268.570000   6   
 14103  0103 29313.120000   1   
 15103  0103 29356.950000   6   
 16103  0103 29399.920000   1   
 17103  0103 29442.710000   1   
 18103  0103 29485.420000   1   
 19103  0103 29528.170000   1   
 20103  0103 29570.400000   1   
 21103  0103 29612.570000   1   
  9108  0108 29087.310000   1   
 10108  0108 29131.520000   1   
 11108  0108 29175.450000   1   
 12108  0108 29218.960000   6   
 13108  0108 29262.100000   6   
 14108  0108 29306.650000   1   
 15108  0108 29350.570000   6   
 16108  0108 29393.550000   1   
 17108  0108 29436.290000   1   
 18108  0108 29478.940000   1   
 19108  0108 29521.830000   1   
 20108  0108 29563.900000   1   
 21108  0108 29606.040000   1   
 22108  0108 29647.920000   1   
  9112  1112 29024.350000 * 2   
 10112  1112 29068.350000 * 2   
 11112  1112 29111.990000 * 2   
 12112  1112 29155.680000 * 2   
 20112  1112 29499.420000 * 6   
 21112  1112 29539.930000 * 2   
 22112  1112 29581.590000 * 2   
 23112  1112 29623.220000 * 2   
  9113  1113 29024.190000   1   
 10113  1113 29068.350000   1   
 11113  1113 29112.200000   1   
 12113  1113 29156.310000   1   
 20113  1113 29500.260000   1   
 21113  1113 29542.370000   1   
 22113  1113 29584.210000   1   
 23113  1113 29625.910000   1   
 14119  0119 29292.050000   1   
 15119  0119 29335.670000   6   
 16119  0119 29378.470000   1   
 17119  0119 29421.200000   1   
 18119  0119 29463.760000   1   
 19119  0119 29506.280000   1   
 20119  0119 29548.470000   1   
 21119  0119 29590.490000   1   
 22119  0119 29632.230000   1   
  9122  1122 29012.310000   1   
 10122  1122 29056.250000   1   
 11122  1122 29099.950000   1   
 12122  1122 29143.370000   6   
 19122  1122 29445.230000   1   
 20122  1122 29487.360000   1   
 21122  1122 29529.350000   1   
 22122  1122 29571.100000   1   
 23122  1122 29612.910000   1   

B. RKR potential energy curve of the 81\Piu state

    v        Gv [cm-1]       R-[A]          R+[A]

-0.49992348    0.0                4.8313034
-0.25          11.599      4.7405574       4.9255472
 0.00          23.192      4.7039375       4.9656678
 1.00          69.460      4.6148079       5.0688273
 2.00         115.564      4.5553459       5.1423627
 3.00         161.501      4.5081024       5.2037245
 4.00         207.269      4.4680082       5.2579831
 5.00         252.866      4.4327449       5.3074577
 6.00         298.290      4.4010220       5.3534402
 7.00         343.538      4.3720337       5.3967376
 8.00         388.609      4.3452369       5.4378942
 9.00         433.500      4.3202450       5.4772978
10.00         478.209      4.2967712       5.5152364
11.00         522.734      4.2745958       5.5519312
12.00         567.072      4.2535460       5.5875560
13.00         611.221      4.2334833       5.6222509
14.00         655.180      4.2142942       5.6561307
15.00         698.946      4.1958844       5.6892909
16.00         742.517      4.1781749       5.7218123
17.00         785.890      4.1610982       5.7537635
18.00         829.064      4.1445963       5.7852042
19.00         872.035      4.1286191       5.8161859
20.00         914.803      4.1131227       5.8467541
21.00         957.365      4.0980683       5.8769492
22.00         999.718      4.0834218       5.9068069
23.00        1041.861      4.0691526       5.9363594
24.00        1083.791      4.0552333       5.9656360