Study of excited electronic states of the $^{39}$KCs molecule correlated with the K($4^2$S)+Cs($5^2$D) asymptote: experiment and theory” J. Szczepkowski, A. Grochola, W. Jastrzebski, P. Kowalczyk, R. Vexiau, N. Bouloufa-Maafa, O. Dulieu Supplementary materials ---------------------------------- Ab initio potential energy curves in [cm^-1] - Hund case (a) coupling R[A] (4)^1Sigma^+ (1)^3Delta (3)^1 Pi (3)^3Pi (4)^3Sigma^+ ---------------------------------------------------------------------------------- 3.06923 24079.8162 20339.5302 22711.7274 24947.7337 27002.1019 3.17506 23074.0990 19875.5022 22059.7965 24268.3247 26034.2593 3.28090 22165.1215 19423.0978 21455.9232 23530.5295 25110.1361 3.38673 21355.0341 18994.6578 20906.0750 22817.5471 24245.9490 3.49257 20642.2724 18599.5816 20414.4742 22156.9664 23452.5229 3.59841 20022.2143 18244.4041 19982.2159 21559.3192 22735.8139 3.70424 19487.9752 17933.0224 19607.1419 21029.0245 22097.8166 3.81008 19031.3338 17667.1209 19284.7876 20566.7588 21537.6075 3.91591 18643.5033 17446.5310 19009.6287 20170.5142 21052.1992 4.02175 18315.7558 17269.7042 18776.0796 19836.4203 20637.3323 4.12758 18039.7721 17134.0565 18578.9914 19559.3404 20287.9995 4.23342 17807.9408 17036.3228 18413.8323 19333.3657 19998.8915 4.33925 17613.5140 16972.8043 18276.6665 19152.1500 19764.6340 4.44509 17450.7619 16939.5952 18164.0900 19009.1680 19579.9996 4.55092 17314.9973 16932.7299 18073.1371 18897.8983 19439.9801 4.65676 17202.5073 16948.3070 18001.2065 18811.9848 19339.8656 4.76259 17110.3978 16982.5845 17946.0079 18745.4154 19275.2493 4.86843 17036.3896 17032.0349 17905.5024 18692.7133 19241.9913 4.97427 16978.6359 17093.3965 17877.8707 18649.1691 19236.1504 5.08010 16935.5627 17163.7005 17861.4737 18611.0426 19253.8137 5.18594 16905.7618 17240.2961 17854.8311 18575.6811 19290.7272 5.29177 16887.9112 17320.8526 17856.5901 18541.4849 19341.3277 5.39761 16880.7363 17403.3658 17865.5179 18507.7432 19395.7855 5.50344 16882.9838 17486.1483 17880.4792 18474.3792 19430.5443 5.60928 16893.4163 17567.8154 17900.4322 18441.6963 19399.2745 5.71511 16910.8147 17647.2669 17924.4207 18410.1722 19294.2100 5.82095 16933.9936 17723.6593 17951.5688 18380.3214 19161.1973 5.92678 16961.8166 17796.3800 17981.0788 18352.6132 19026.4333 6.03262 16993.2170 17865.0161 18012.2309 18327.4379 18898.6292 6.13846 17027.2132 17929.3229 18044.3803 18305.0943 18780.8065 6.24429 17062.9264 17989.1963 18076.9595 18285.7926 18674.1396 6.35013 17099.5871 18044.6427 18109.4746 18269.6624 18579.1343 6.45596 17136.5467 18095.7539 18141.5064 18256.7644 18496.0272 6.56180 17173.2741 18142.6872 18172.7081 18247.0990 18424.9196 6.66763 17209.3556 18185.6431 18202.8019 18240.6170 18365.7916 6.77347 17244.4886 18224.8521 18231.5765 18237.2230 18318.4511 6.87930 17278.4714 18260.5616 18258.8807 18236.7839 18282.4585 6.98514 17311.1936 18293.0258 18284.6187 18239.1289 18257.0519 7.09097 17342.6241 18322.4969 18308.7417 18244.0559 18241.1482 7.19681 17372.7981 18349.2218 18331.2412 18251.3310 18233.4109 7.30265 17401.8103 18373.4378 18352.1419 18260.6954 18232.3782 7.40848 17429.7971 18395.3683 18371.4935 18271.8686 18236.6100 7.51432 17456.9316 18415.2226 18389.3642 18284.5549 18244.7978 7.62015 17483.4141 18433.1961 18405.8356 18298.4521 18255.8281 7.72599 17509.4640 18449.4672 18420.9964 18313.2596 18268.7960 7.83182 17535.3133 18464.2009 18434.9399 18328.6872 18282.9959 7.93766 17561.1997 18477.5474 18447.7590 18344.4641 18297.8894 8.04349 17587.3618 18489.6419 18459.5448 18360.3439 18313.0758 8.14933 17614.0337 18500.6095 18470.3861 18376.1122 18328.2637 8.25516 17641.4368 18510.5610 18480.3647 18391.5861 18343.2430 8.36100 17669.7757 18519.5977 18489.5584 18406.6171 18357.8681 8.46684 17699.2285 18527.8105 18498.0388 18421.0898 18372.0394 8.57267 17729.9390 18535.2808 18505.8714 18434.9189 18385.6915 8.67851 17762.0085 18542.0826 18513.1160 18448.0468 18398.7875 8.78434 17795.4846 18548.2822 18519.8268 18460.4390 18411.3061 8.89018 17830.3552 18553.9383 18526.0525 18472.0807 18423.2408 8.99601 17866.5426 18559.1045 18531.8367 18482.9728 18434.5940 9.10185 17903.9013 18563.8288 18537.2192 18493.1295 18445.3758 9.20768 17942.2200 18568.1537 18542.2352 18502.5736 18455.6007 9.31352 17981.2298 18572.1180 18546.9162 18511.3350 18465.2857 9.41935 18020.6154 18575.7561 18551.2909 18519.4483 18474.4509 9.52519 18060.0301 18579.0988 18555.3843 18526.9500 18483.1162 9.63103 18099.1120 18582.1739 18559.2191 18533.8791 18491.3027 9.73686 18137.5023 18585.0064 18562.8155 18540.2741 18499.0321 9.84270 18174.8612 18587.6184 18566.1921 18546.1731 18506.3252 9.94853 18210.8820 18590.0299 18569.3651 18551.6128 18513.2036 10.0544 18245.3035 18592.2589 18572.3492 18556.6287 18519.6850 10.1602 18277.9164 18594.3215 18575.1577 18561.2539 18525.7920 10.2660 18308.5679 18596.2320 18577.8030 18565.5201 18531.5425 10.3719 18337.1613 18598.0037 18580.2956 18569.4563 18536.9549 10.4777 18363.6532 18599.6480 18582.6456 18573.0895 18542.0472 10.5835 18388.0481 18601.1758 18584.8625 18576.4454 18546.8372 10.6894 18410.3919 18602.5964 18586.9542 18579.5465 18551.3391 10.7952 18430.7592 18603.9185 18588.9289 18582.4147 18555.5709 10.9011 18449.2511 18605.1501 18590.7935 18585.0690 18559.5476 11.0069 18465.9844 18606.2982 18592.5545 18587.5277 18563.2832 11.1127 18481.0849 18607.3693 18594.2184 18589.8066 18566.7917 11.2186 18494.6831 18608.3695 18595.7907 18591.9211 18570.0867 11.3244 18506.9083 18609.3040 18597.2769 18593.8846 18573.1804 11.4302 18517.8864 18610.1778 18598.6820 18595.7098 18576.0853 11.5361 18527.7373 18610.9954 18600.0108 18597.4078 18578.8132 11.6419 18536.5719 18611.7612 18601.2677 18598.9891 18581.3757 11.7477 18544.4980 18612.4788 18602.4568 18600.4630 18583.7796 11.8536 18551.6076 18613.1517 18603.5821 18601.8381 18586.0383 11.9594 18557.9880 18613.7833 18604.6473 18603.1225 18588.1602 12.0652 18563.7179 18614.3765 18605.6557 18604.3230 18590.1542 12.1711 18568.8677 18614.9341 18606.6108 18605.4462 18592.0280 12.2769 18573.5013 18615.4585 18607.5155 18606.4981 18593.7895 12.3827 18577.6738 18615.9520 18608.3726 18607.4842 18595.4465 12.4886 18581.4367 18616.4169 18609.1850 18608.4093 18597.0051 12.5944 18584.8344 18616.8550 18609.9551 18609.2781 18598.4720 12.7003 18587.9065 18617.2683 18610.6854 18610.0945 18599.8533 12.8061 18590.6883 18617.6584 18611.3781 18610.8627 18601.1550 12.9119 18593.2120 18618.0268 18612.0352 18611.5856 18602.3812 13.0178 18595.5041 18618.3751 18612.6589 18612.2668 18603.5378 13.1236 18597.5885 18618.7046 18613.2509 18612.9089 18604.6301 13.2294 18599.4911 18619.0164 18613.8130 18613.5149 18605.6587 13.3353 18601.2268 18619.3118 18614.3469 18614.0869 18606.6312 13.4411 18602.8144 18619.5918 18614.8542 18614.6276 18607.5505 13.5469 18604.2691 18619.8574 18615.3361 18615.1386 18608.4195 13.6528 18605.6046 18620.1096 18615.7942 18615.6221 18609.2417 13.7586 18606.8324 18620.3491 18616.2298 18616.0798 18610.0198 13.8644 18607.9636 18620.5768 18616.6440 18616.5133 18610.7571 13.9703 18609.0076 18620.7933 18617.0381 18616.9242 18611.4552 14.0761 18609.9724 18620.9995 18617.4130 18617.3137 18612.1179 14.1819 18610.8657 18621.1959 18617.7698 18617.6833 18612.7462 14.2878 18611.6944 18621.3831 18618.1096 18618.0342 18613.3429 14.3936 18612.4646 18621.5616 18618.4330 18618.3674 18613.9091 14.4995 18613.1812 18621.7320 18618.7411 18618.6840 18614.4473 14.6053 18613.8492 18621.8948 18619.0347 18618.9849 18614.9588 14.7111 18614.4728 18622.0502 18619.3145 18619.2712 18615.4449 14.8170 18615.0556 18622.1989 18619.5812 18619.5434 18615.9075 14.9228 18615.6010 18622.3411 18619.8355 18619.8026 18616.3480 15.0286 18616.1123 18622.4771 18620.0782 18620.0495 18616.7666 15.1345 18616.5909 18622.6074 18620.3096 18620.2846 18617.1664 15.2403 18617.0420 18622.7323 18620.5305 18620.5087 18617.5454 15.3461 18617.4660 18622.8519 18620.7414 18620.7224 18617.9064 15.4520 18617.8648 18622.9666 18620.9427 18620.9262 18618.2505 15.5578 18618.2404 18623.0766 18621.1351 18621.1207 18618.5780 15.6636 18618.5944 18623.1821 18621.3189 18621.3062 18618.8901 15.7695 18618.9284 18623.2834 18621.4945 18621.4835 18619.1873 15.8753 18619.2431 18623.3806 18621.6624 18621.6528 18619.4706 15.9812 18619.5410 18623.4740 18621.8229 18621.8146 18619.7399 16.0870 18619.8224 18623.5636 18621.9765 18621.9692 18619.9963 16.1928 18620.0884 18623.6498 18622.1234 18622.1170 18620.2405 16.2987 18620.3402 18623.7325 18622.2640 18622.2584 18620.4729 16.4045 18620.5782 18623.8120 18622.3986 18622.3938 18620.6943 16.5103 18620.8037 18623.8885 18622.5275 18622.5232 18620.9052 16.6162 18621.0172 18623.9619 18622.6509 18622.6472 18621.1059 16.7220 18621.2196 18624.0326 18622.7691 18622.7659 18621.2971 16.9337 18621.5937 18624.1658 18622.9910 18622.9886 18621.6528 17.0395 18621.7666 18624.2287 18623.0952 18623.0930 18621.8182 17.1453 18621.9310 18624.2891 18623.1950 18623.1931 18621.9760 17.2512 18622.0872 18624.3473 18623.2908 18623.2891 18622.1265 17.3570 18622.2360 18624.4033 18623.3826 18623.3813 18622.2702 17.4628 18622.3776 18624.4572 18623.4709 18623.4696 18622.4076 17.5687 18622.5128 18624.5091 18623.5556 18623.5545 18622.5387 17.6745 18622.6417 18624.5591 18623.6369 18623.6360 18622.6643 17.7804 18622.7648 18624.6073 18623.7151 18623.7142 18622.7845 17.8862 18622.8827 18624.6537 18623.7902 18623.7895 18622.8996 17.9920 18622.9953 18624.6985 18623.8624 18623.8618 18623.0102 18.0979 18623.1033 18624.7417 18623.9318 18623.9313 18623.1162 18.2037 18623.2068 18624.7833 18623.9987 18623.9982 18623.2181 18.3095 18623.3063 18624.8235 18624.0630 18624.0625 18623.3161 18.4154 18623.4013 18624.8624 18624.1249 18624.1245 18623.4107 18.5212 18623.4935 18624.8998 18624.1845 18624.1842 18623.5011 18.6270 18623.5818 18624.9361 18624.2420 18624.2417 18623.5885 18.7329 18623.6670 18624.9711 18624.2974 18624.2972 18623.6727 18.8387 18623.7490 18625.0049 18624.3509 18624.3506 18623.7539 18.9445 18623.8281 18625.0376 18624.4024 18624.4022 18623.8324 19.0504 18623.9043 18625.0693 18624.4522 18624.4520 18623.9080 19.1562 18623.9779 18625.0999 18624.5002 18624.5001 18623.9810 19.2621 18624.0487 18625.1296 18624.5467 18624.5465 18624.0516 19.3679 18624.1172 18625.1583 18624.5915 18624.5914 18624.1197 19.4737 18624.1833 18625.1861 18624.6349 18624.6348 18624.1854 19.5796 18624.2471 18625.2131 18624.6768 18624.6767 18624.2488 19.6854 18624.3086 18625.2392 18624.7174 18624.7173 18624.3101 19.7912 18624.3679 18625.2645 18624.7567 18624.7566 18624.3692 19.8971 18624.4249 18625.2890 18624.7947 18624.7946 18624.4264 20.0029 18624.4802 18625.3127 18624.8315 18624.8315 18624.4814 20.1087 18624.5334 18625.3358 18624.8672 18624.8671 18624.5344 20.2146 18624.5845 18625.3581 18624.9018 18624.9017 18624.5854 20.3204 18624.6339 18625.3797 18624.9352 18624.9352 18624.6345 20.4262 18624.6813 18625.4007 18624.9677 18624.9676 18624.6819 20.5321 18624.7269 18625.4210 18624.9991 18624.9991 18624.7274 20.6379 18624.7708 18625.4407 18625.0297 18625.0296 18624.7712 20.7437 18624.8129 18625.4598 18625.0593 18625.0592 18624.8132 20.8496 18624.8533 18625.4783 18625.0880 18625.0879 18624.8536 20.9554 18624.8921 18625.4962 18625.1158 18625.1158 18624.8924 21.0613 18624.9293 18625.5136 18625.1428 18625.1428 18624.9295 21.1671 18624.9650 18625.5304 18625.1690 18625.1690 18624.9651 21.2729 18624.9992 18625.5467 18625.1945 18625.1945 18624.9993 21.3788 18625.0319 18625.5625 18625.2192 18625.2191 18625.0320 21.4846 18625.0632 18625.5777 18625.2431 18625.2431 18625.0633 21.5904 18625.0932 18625.5925 18625.2663 18625.2663 18625.0933 21.6963 18625.1219 18625.6068 18625.2888 18625.2888 18625.1220 21.8021 18625.1493 18625.6207 18625.3107 18625.3107 18625.1495 21.9079 18625.1756 18625.6340 18625.3319 18625.3319 18625.1757 22.0138 18625.2007 18625.6470 18625.3525 18625.3525 18625.2008 22.1196 18625.2248 18625.6595 18625.3725 18625.3724 18625.2248 22.2254 18625.2478 18625.6716 18625.3918 18625.3918 18625.2478 22.3313 18625.2698 18625.6833 18625.4106 18625.4106 18625.2699 22.4371 18625.2909 18625.6946 18625.4288 18625.4288 18625.2910 22.5429 18625.3112 18625.7055 18625.4465 18625.4465 18625.3112 22.6488 18625.3306 18625.7160 18625.4636 18625.4636 18625.3306 22.7546 18625.3492 18625.7262 18625.4803 18625.4802 18625.3492 22.8605 18625.3671 18625.7361 18625.4964 18625.4963 18625.3671 22.9663 18625.3843 18625.7456 18625.5120 18625.5120 18625.3843 23.0721 18625.4008 18625.7548 18625.5272 18625.5271 18625.4008 23.1780 18625.4168 18625.7637 18625.5419 18625.5418 18625.4168 23.2838 18625.4322 18625.7722 18625.5561 18625.5561 18625.4321 23.3896 18625.4470 18625.7805 18625.5700 18625.5699 18625.4470 23.4955 18625.4614 18625.7886 18625.5834 18625.5833 18625.4614 23.6013 18625.4753 18625.7963 18625.5964 18625.5964 18625.4753 23.7071 18625.4888 18625.8039 18625.6091 18625.6090 18625.4888 23.8130 18625.5019 18625.8111 18625.6213 18625.6213 18625.5019