Experimentally determined energies of rovibrational levels of the 4{singlet}{Sigma}+{ungerade} state in Na2. Zero of energy corresponds to the bottom of the ground state potential. Asterisks denote levels excluded from the fit of the potential energy curve. v J E(cm-1) v J E(cm-1) 0 12 33243.31 2 42 33614.09 1 12 33344.81 3 42 33701.39 2 12 33441.85 4 42 33781.18 3 12 33533.43 5 42 33853.41 6 12 33767.83 6 42 33919.76 7 12 33834.93 7 42 33983.12 8 12 33899.66 8 42 34045.00 9 12 33963.10 9 42 34106.01 10 12 34025.57 10 42 34166.34 11 12 34087.32 11 42 34226.16 18 12 34502.54 12 42 34285.42 19 12 34559.58 13 42 34344.04 21 12 34671.68 15 42 34459.92 22 12 34726.67 16 42 34517.04 23 12 34780.82 17 42 34573.66 0 14 33249.18 18 42 34629.73 1 14 33350.61 19 42 34684.98* 2 14 33447.52 24 42 34951.74 3 14 33539.00 25 42 35002.47 6 14 33772.85 26 42 35051.91 7 14 33839.84 27 42 35100.23 8 14 33904.51 28 42 35147.08 9 14 33967.82 29 42 35192.47 10 14 34030.25 30 42 35236.15 11 14 34091.85 31 42 35277.98 16 14 34391.09 32 42 35317.56 17 14 34449.23 37 42 35389.28 18 14 34506.73 41 42 35420.39 19 14 34563.69 45 42 35447.26* 21 14 34675.68 49 42 35470.03 22 14 34730.64 51 42 35482.07 23 14 34784.79 52 42 35486.35 1 16 33357.16 53 42 35491.96 2 16 33453.96 54 42 35498.20 3 16 33545.32 55 42 35504.68 4 16 33629.99 56 42 35511.43 5 16 33707.50 57 42 35518.60 1 18 33364.64 58 42 35525.99 2 18 33461.36 60 42 35541.62 3 18 33552.48 61 42 35549.69 4 18 33637.04 62 42 35558.01 5 18 33714.28 63 42 35566.46 7 18 33851.79 64 42 35575.18 0 24 33291.55 65 42 35584.11 1 24 33392.26 66 42 35593.15 2 24 33488.43 67 42 35602.44 4 24 33662.73 68 42 35611.80 5 24 33739.20 70 42 35631.38* 6 24 33809.13 71 42 35641.11 0 26 33302.62 72 42 35651.17 1 26 33403.12 73 42 35661.44 2 26 33499.13 74 42 35671.67 4 26 33672.87 75 42 35682.10 5 26 33748.87 76 42 35692.71 2 27 33504.86 77 42 35703.40 3 27 33594.97 0 43 33431.15 4 27 33678.21 3 43 33710.06 5 27 33754.06 0 44 33440.55 6 27 33823.66 1 44 33538.86 7 27 33889.33 2 44 33632.07 8 27 33952.96 3 44 33718.90 9 27 34015.47 4 44 33798.10 10 27 34077.22 5 44 33869.64 11 27 34138.16 6 44 33935.51 12 27 34198.58 7 44 33998.50 13 27 34258.38 8 44 34060.12 14 27 34317.61 9 44 34120.89 15 27 34376.49 10 44 34181.03 16 27 34434.52 11 44 34240.63 17 27 34492.16 12 44 34299.82 18 27 34549.13 13 44 34358.13 19 27 34605.62 14 44 34416.15 20 27 34661.39 15 44 34473.63 21 27 34716.58 16 44 34530.65 23 27 34824.60 18 44 34643.03 24 27 34877.43 19 44 34698.25 25 27 34929.19 20 44 34752.98 0 28 33314.53 23 44 34912.57 1 28 33414.96 24 44 34964.00 2 28 33510.67 25 44 35014.46 4 28 33683.78 26 44 35063.74 5 28 33759.39 27 44 35111.84 6 28 33828.78 28 44 35158.44 7 28 33894.34 29 44 35203.62 11 28 34142.88 30 44 35246.90 0 29 33320.81 31 44 35288.52 1 29 33421.12 32 44 35327.70 2 29 33516.78 34 44 35364.46 3 29 33606.59 38 44 35398.50 4 29 33689.48 42 44 35429.05 5 29 33764.91 46 44 35455.68 6 29 33834.23 49 44 35476.72 7 29 33899.56 51 44 35485.33 8 29 33963.06 52 44 35490.31 9 29 34025.38 53 44 35495.64 10 29 34086.93 54 44 35501.81 11 29 34147.80 55 44 35508.37 12 29 34208.06 56 44 35515.15 13 29 34267.76 57 44 35522.37 14 29 34326.89 58 44 35529.78 15 29 34385.44 59 44 35537.41 16 29 34443.57 60 44 35545.34 17 29 34501.08 61 44 35553.37 18 29 34557.96 62 44 35561.83 19 29 34614.31 63 44 35570.36 20 29 34670.02 64 44 35579.08 21 29 34725.09 65 44 35588.00 23 29 34832.92 66 44 35597.10 24 29 34885.95 67 44 35606.39* 25 29 34937.17 68 44 35615.77 0 30 33327.32 69 44 35625.39 1 30 33427.54 70 44 35635.13 4 30 33695.40 71 44 35644.94* 5 30 33770.63 72 44 35655.17 6 30 33839.65 73 44 35665.32 11 30 34152.79 74 44 35675.60 0 31 33334.04 75 44 35686.15 1 31 33434.12 76 44 35696.79 2 31 33529.47 77 44 35707.51 4 31 33701.50 0 46 33460.05 5 31 33776.51 1 46 33558.01 6 31 33845.33 2 46 33650.83 7 31 33910.49 3 46 33737.14 0 37 33378.86 4 46 33815.66 1 37 33478.20 5 46 33886.57 2 37 33572.67 13 46 34372.84 3 37 33661.08 15 46 34488.00 4 37 33742.17 0 48 33480.36 6 37 33883.37 1 48 33578.03 7 37 33947.57 2 48 33670.37 8 37 34010.14 4 48 33834.00 9 37 34071.67 5 48 33904.14 14 37 34370.18 6 48 33969.05 15 37 34428.26 11 48 34271.41 16 37 34485.74 12 48 34329.98 20 37 34710.14 13 48 34388.17 21 37 34764.77 15 48 34502.94 22 37 34818.58 16 48 34559.57 23 37 34871.51 0 54 33546.15 28 37 35120.93 1 54 33642.65 0 39 33395.42 3 54 33817.42 1 39 33494.50 4 54 33893.06 2 39 33588.65 5 54 33961.08 3 39 33676.68 6 54 34024.29 4 39 33757.29 9 54 34204.95 6 39 33897.41 10 54 34263.86 7 39 33961.33 11 54 34322.29 8 39 34023.61 12 54 34380.27 9 39 34084.94 18 54 34718.12* 10 39 34145.54 20 54 34826.01 14 39 34382.47 2 55 33744.91 15 39 34440.45 3 55 33828.35 16 39 34497.84 0 56 33569.70 17 39 34554.67 1 56 33665.82 22 39 34829.76 3 56 33839.30 23 39 34882.59 4 56 33914.12 27 39 35083.74 5 56 33981.35 0 40 33403.95 6 56 34043.99 6 40 33904.68 9 56 34223.66 7 40 33968.38 10 56 34282.24 8 40 34030.55 11 56 34340.51 0 41 33412.82 12 56 34398.21 3 41 33692.99 19 56 34788.71 4 41 33773.03 20 56 34842.30 0 42 33421.84 2 57 33767.81 1 42 33520.52 3 57 33850.81*