A supplementary material to the paper The 4^1\Sigma^+ electronic state of KLi molecule Authors: J.Szczepkowski, A.Grochola, W.Jastrzebski(*), P.Kowalczyk (*) e-mail address jastr@ifpan.edu.pl ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Table 1. Experimental energies of rovibrational levels in the 4^1\Sigma^+ state (Eexp) and the corresponding values calculated from the IPA potential (Ecalc), in cm-1. Diff are the differences Eexp-Ecalc. All levels refer to the 39K7Li isotopologue. v J Eexp Ecalc Diff ================================================== 25 7 23403.00845 23403.04764 -.03919 26 7 23434.13845 23434.08985 .04860 27 7 23468.87845 23468.89343 -.01498 28 7 23506.60845 23506.68201 -.07356 29 7 23545.25845 23545.31364 -.05519 30 7 23584.23845 23584.18479 .05366 31 7 23623.61845 23623.54768 .07077 32 7 23663.70845 23663.69412 .01433 33 7 23704.61845 23704.60850 .00995 34 7 23746.18845 23746.11571 .07274 35 7 23788.21845 23788.08182 .13663 36 7 23830.71845 23830.46920 .24925 37 7 23873.48845 23873.28209 .20636 43 7 24138.40845 24138.38997 .01848 44 7 24183.66845 24183.72691 -.05846 46 7 24275.65845 24275.22258 .43587 47 7 24321.08845 24321.34312 -.25467 48 7 24365.55845 24367.68101 -2.12256 49 7 24418.14845 24414.21147 3.93698 50 7 24460.76845 24460.92180 -.15335 51 7 24505.18845 24507.79520 -2.60675 52 7 24547.61845 24554.81548 -7.19703 53 7 24603.16845 24601.96882 1.19963 25 9 23406.85845 23406.86197 -.00352 26 9 23437.97845 23437.91190 .06655 27 9 23472.33845 23472.36188 -.02343 28 9 23509.95845 23510.02393 -.06548 29 9 23548.61845 23548.66514 -.04669 30 9 23587.60845 23587.55733 .05112 31 9 23626.96845 23626.90141 .06704 32 9 23667.02845 23667.00688 .02157 33 9 23707.78845 23707.88699 -.09854 34 9 23749.46845 23749.37406 .09439 35 9 23791.49845 23791.32627 .17218 36 9 23833.93845 23833.69822 .24023 37 9 23876.60845 23876.49198 .11647 43 9 24141.52845 24141.47511 .05334 44 9 24186.78845 24186.79140 -.00295 46 9 24278.71845 24278.24525 .47320 47 9 24324.20845 24324.34582 -.13737 48 9 24368.82845 24370.66452 -1.83607 49 9 24421.66845 24417.17614 4.49231 50 9 24463.88845 24463.86781 .02064 51 9 24508.39845 24510.72231 -2.32386 52 9 24551.06845 24557.72413 -6.65568 53 9 24606.60845 24604.85949 1.74896 25 12 23414.10120 23414.12865 -.02745 26 12 23445.42120 23445.39569 .02551 27 12 23479.17120 23479.16240 .00880 28 12 23516.46120 23516.51950 -.05830 29 12 23555.09120 23555.15729 -.06609 30 12 23594.10120 23594.09457 .00663 31 12 23633.43120 23633.41296 .01824 32 12 23673.43120 23673.44197 -.01077 33 12 23714.19120 23714.25242 -.06122 44 12 24192.72120 24192.74031 -.01911 46 12 24284.66120 24284.11297 .54823 47 12 24330.20120 24330.17451 .02669 48 12 24375.13120 24376.45570 -1.32450 50 12 24470.02120 24469.58614 .43506 51 12 24514.55120 24516.40391 -1.85271 25 14 23419.89120 23419.93052 -.03932 26 14 23451.60120 23451.55652 .04468 27 14 23484.81120 23484.80089 .01031 28 14 23521.80120 23521.84832 -.04712 29 14 23560.39120 23560.45711 -.06591 30 14 23599.41120 23599.43259 -.02139 31 14 23638.76120 23638.74060 .02060 32 14 23678.70120 23678.71135 -.01015 33 14 23719.41120 23719.46228 -.05108 44 14 24197.61820 24197.60776 .01044 46 14 24289.44120 24288.91402 .52718 47 14 24335.06120 24334.94338 .11782 47 14 24335.05498 24334.94338 .11160 48 14 24380.17120 24381.19363 -1.02243 50 14 24475.00120 24474.26438 .73682 51 14 24519.51120 24521.05207 -1.54087 25 15 23423.05404 23423.09722 -.04318 26 15 23455.03404 23454.98278 .05126 27 15 23488.02404 23487.96471 .05933 28 15 23524.80404 23524.81683 -.01279 29 15 23563.33404 23563.39758 -.06354 30 15 23602.40404 23602.39361 .01043 31 15 23641.73404 23641.69986 .03418 32 15 23681.65404 23681.64036 .01368 33 15 23722.34404 23722.35752 -.01348 34 15 23763.74404 23763.74143 .00261 35 15 23805.75404 23805.62818 .12586 36 15 23848.18404 23847.93539 .24865 37 15 23890.78549 23890.64992 .13557 38 15 23933.76049 23933.78118 -.02069 39 15 23977.09049 23977.32721 -.23672 40 15 24020.78049 24021.25913 -.47864 41 15 24066.22049 24065.54361 .67688 42 15 24110.04049 24110.15830 -.11781 43 15 24155.05049 24155.08631 -.03582 44 15 24200.38749 24200.31195 .07554 45 15 24244.58049 24245.81619 -1.23570 25 16 23426.34710 23426.43129 -.08419 26 16 23458.64710 23458.63308 .01402 27 16 23491.40710 23491.36499 .04211 28 16 23527.97710 23527.99122 -.01412 29 16 23566.48710 23566.53160 -.04450 30 16 23605.55710 23605.54826 .00884 31 16 23644.92710 23644.85564 .07146 32 16 23684.77710 23684.76579 .01131 33 16 23725.43710 23725.44657 -.00947 34 16 23766.80710 23766.80531 .00179 44 16 24203.20498 24203.19644 .00854 47 16 24340.58498 24340.41873 .16625 25 17 23429.89404 23429.92572 -.03168 26 17 23462.54404 23462.49991 .04413 27 17 23495.07404 23495.00692 .06712 28 17 23531.36404 23531.37463 -.01059 29 17 23569.83404 23569.85933 -.02529 30 17 23608.88404 23608.89570 -.01166 31 17 23648.27404 23648.20744 .06660 32 17 23688.10404 23688.08776 .01628 33 17 23728.68404 23728.72964 -.04560 34 17 23770.04404 23770.06043 -.01639 35 17 23812.04404 23811.91496 .12908 36 17 23854.40404 23854.19468 .20936 37 17 23897.04504 23896.87695 .16809 38 17 23940.00049 23939.96945 .03104 39 17 23983.29049 23983.47404 -.18355 40 17 24026.88049 24027.36583 -.48534 41 17 24073.49049 24071.61139 1.87910 42 17 24116.14049 24116.18677 -.04628 43 17 24161.03849 24161.07524 -.03675 44 17 24206.31404 24206.26123 .05281 45 17 24251.26049 24251.72518 -.46469 25 18 23433.51710 23433.57406 -.05696 26 18 23466.59710 23466.57351 .02359 27 18 23498.95710 23498.89535 .06175 28 18 23534.99710 23534.97096 .02614 29 18 23573.33710 23573.38121 -.04411 30 18 23612.42710 23612.43504 -.00794 31 18 23651.81710 23651.75467 .06243 32 18 23691.63710 23691.60633 .03077 33 18 23732.17710 23732.20700 -.02990 34 18 23773.50710 23773.50686 .00024 43 18 24164.26576 24164.34190 -.07614 44 18 24209.51576 24209.50633 .00943 45 18 24254.68576 24254.94835 -.26259 46 18 24301.24576 24300.65070 .59506 54 18 24672.47576 24673.39268 -.91692 55 18 24716.25576 24720.61059 -4.35483 56 18 24758.97576 24767.91448 -8.93872 57 18 24814.83576 24815.29716 -.46140 27 20 23507.47645 23507.42606 .05039 28 20 23542.85645 23542.82225 .03420 29 20 23580.96645 23581.01128 -.04483 30 20 23620.05645 23620.08609 -.02964 31 20 23659.45645 23659.43224 .02421 32 20 23699.26645 23699.23307 .03338 33 20 23739.71645 23739.74570 -.02925 43 20 24171.34576 24171.41951 -.07375 44 20 24216.53576 24216.53734 -.00158 45 20 24261.87576 24261.93206 -.05630 46 20 24308.16576 24307.58655 .57921 54 20 24679.83576 24679.97801 -.14225 55 20 24723.45576 24727.15648 -3.70072 56 20 24766.50576 24774.42251 -7.91675 57 20 24823.01576 24821.76830 1.24746 26 21 23479.89450 23479.90933 -.01483 27 21 23512.08950 23512.07073 .01877 28 21 23547.12550 23547.08943 .03607 29 21 23585.07950 23585.12276 -.04326 29 21 23585.08950 23585.12276 -.03326 30 21 23624.16450 23624.19633 -.03183 31 21 23663.56450 23663.56062 .00388 32 21 23703.35950 23703.34087 .01863 33 21 23743.76950 23743.80762 -.03812 34 21 23784.94450 23784.99533 -.05083 35 21 23826.80950 23826.76137 .04813 36 21 23869.08950 23868.97525 .11425 37 21 23911.74950 23911.58668 .16282 45 21 24265.65950 24265.69257 -.03307 46 21 24311.85950 24311.32139 .53811 48 21 24403.17950 24403.30100 -.12150 49 21 24448.27950 24449.60490 -1.32540 50 21 24498.13950 24496.09124 2.04826 51 21 24542.56950 24542.73870 -.16920 52 21 24587.06950 24589.53663 -2.46713 27 22 23516.99645 23516.96499 .03146 28 22 23551.63645 23551.59392 .04253 29 22 23589.43645 23589.43523 .00122 30 22 23628.48645 23628.49569 -.00924 31 22 23667.88645 23667.88054 .00591 32 22 23707.69645 23707.64445 .05200 33 22 23748.05645 23748.06492 -.00847 43 22 24179.06876 24179.22266 -.15390 44 22 24224.26876 24224.28935 -.02059 45 22 24269.64876 24269.63219 .01657 46 22 24315.81876 24315.23418 .58458 47 22 24361.48876 24361.08415 .40461 52 22 24591.18876 24593.29813 -2.10937 53 22 24631.80876 24640.20749 -8.39873 54 22 24687.97876 24687.23711 .74165 55 22 24731.37876 24734.37164 -2.99288 56 22 24774.70876 24781.59571 -6.88695 58 22 24872.07876 24876.27977 -4.20101 26 23 23489.56950 23489.58582 -.01632 27 23 23522.11950 23522.10143 .01807 27 23 23522.11098 23522.10143 .00955 27 23 23522.14398 23522.10143 .04255 28 23 23556.38950 23556.34375 .04575 29 23 23593.90950 23593.95229 -.04279 29 23 23593.90398 23593.95229 -.04831 30 23 23632.93450 23632.98403 -.04953 31 23 23672.39398 23672.39072 .00326 32 23 23712.15650 23712.14320 .01330 33 23 23752.50950 23752.51782 -.00832 34 23 23793.55950 23793.61411 -.05461 35 23 23835.33950 23835.31968 .01982 36 23 23877.59250 23877.49302 .09948 37 23 23920.21950 23920.06610 .15340 38 23 23963.13398 23963.02647 .10751 39 23 24006.28638 24006.38106 -.09468 40 23 24049.71638 24050.12231 -.40593 41 23 24093.09638 24094.22263 -1.12625 42 23 24138.78638 24138.65324 .13314 43 23 24183.28638 24183.39622 -.10984 44 23 24228.41898 24228.43566 -.01668 45 23 24273.79638 24273.75088 .04550 46 23 24319.82950 24319.32494 .50456 47 23 24365.51950 24365.14675 .37275 48 23 24411.22950 24411.19563 .03387 49 23 24456.04950 24457.44840 -1.39890 50 23 24506.51950 24503.88451 2.63499 51 23 24550.67950 24550.48200 .19750 52 23 24595.44950 24597.23034 -1.78084 43 24 24187.64876 24187.75105 -.10229 44 24 24232.68876 24232.76211 -.07335 45 24 24278.09071 24278.04862 .04209 46 24 24324.18876 24323.59365 .59511 47 24 24369.45371 24369.38606 .06765 48 24 24415.51371 24415.40599 .10772 49 24 24460.57371 24461.63129 -1.05758 51 24 24554.98371 24554.61134 .37237 52 24 24599.83771 24601.33320 -1.49549 53 24 24641.96371 24648.19044 -6.22673 54 24 24696.98876 24695.16963 1.81913 55 24 24740.02876 24742.25559 -2.22683 56 24 24783.57876 24789.43350 -5.85474 58 24 24880.83876 24884.02958 -3.19082 26 25 23499.74098 23499.76531 -.02433 27 25 23533.06056 23533.04807 .01249 28 25 23566.66056 23566.61156 .04900 29 25 23603.61398 23603.62012 -.00614 30 25 23642.48256 23642.52932 -.04676 31 25 23681.96656 23681.97650 -.00994 32 25 23721.72656 23721.72274 .00382 33 25 23761.98698 23762.01081 -.02383 34 25 23802.95056 23803.00363 -.05307 35 25 23844.59556 23844.63488 -.03932 36 25 23886.82398 23886.76014 .06384 37 25 23929.43756 23929.29236 .14520 38 25 23972.32638 23972.20571 .12067 39 25 24015.45638 24015.50391 -.04753 40 25 24058.83638 24059.18548 -.34910 41 25 24102.30638 24103.22769 -.92131 42 25 24148.07638 24147.60122 .47516 43 25 24192.15638 24192.28707 -.13069 44 25 24237.17056 24237.26868 -.09812 45 25 24282.54056 24282.52537 .01519 47 25 24374.21056 24373.80208 .40848 48 25 24420.02056 24419.79173 .22883 49 25 24465.28056 24465.98826 -.70770 51 25 24559.49056 24558.91242 .57814 52 25 24604.46056 24605.60670 -1.14614 53 25 24647.06056 24652.43615 -5.37559 26 26 23505.02363 23505.01885 .00478 27 26 23538.79363 23538.82065 -.02702 28 26 23572.18363 23572.14302 .04061 29 26 23608.77363 23608.78396 -.01033 30 26 23647.52363 23647.58870 -.06507 34 26 23807.89363 23807.98838 -.09475 35 26 23849.48363 23849.57667 -.09304 36 26 23891.70363 23891.67426 .02937 37 26 23934.31363 23934.18477 .12886 38 26 23977.20363 23977.07433 .12930 45 26 24287.12371 24287.18109 -.05738 47 26 24378.71359 24378.39484 .31875 48 26 24424.58059 24424.35286 .22773 49 26 24470.00059 24470.51929 -.51870 51 26 24564.11359 24563.38520 .72839 52 26 24609.11359 24610.05077 -.93718 53 26 24652.40371 24656.85131 -4.44760 54 26 24706.90359 24703.77527 3.12832 26 27 23510.41056 23510.37348 .03708 27 27 23544.76756 23544.76192 .00564 28 27 23577.99184 23577.94419 .04765 29 27 23614.19356 23614.17870 .01486 30 27 23652.82056 23652.84225 -.02169 31 27 23692.28056 23692.30794 -.02738 32 27 23732.08056 23732.07018 .01038 33 27 23772.27056 23772.28584 -.01528 34 27 23813.09584 23813.16697 -.07113 35 27 23854.65056 23854.70828 -.05772 36 27 23896.80056 23896.77527 .02529 37 27 23939.36556 23939.26292 .10264 38 27 23982.28056 23982.12851 .15205 39 27 24025.39056 24025.36870 .02186 43 27 24201.80056 24201.90247 -.10191 44 27 24246.64556 24246.82188 -.17632 45 27 24291.97056 24292.01572 -.04516 45 27 24291.91284 24292.01572 -.10288 46 27 24337.24056 24337.46736 -.22680 47 27 24383.50056 24383.16432 .33624 48 27 24429.38056 24429.08940 .29116 49 27 24475.03056 24475.22438 -.19382 51 27 24568.91056 24568.02962 .88094 52 27 24613.71056 24614.66538 -.95482 53 27 24656.68056 24661.43588 -4.75532 25 28 23477.68034 23477.69489 -.01455 26 28 23515.88063 23515.82626 .05437 27 28 23550.83634 23550.84683 -.01049 28 28 23584.05634 23584.01300 .04334 29 28 23619.84634 23619.81410 .03224 30 28 23658.26634 23658.29356 -.02722 31 28 23697.71634 23697.75101 -.03467 32 28 23737.54634 23737.52800 .01834 33 28 23777.71634 23777.71553 .00081 34 28 23818.46963 23818.53972 -.07009 35 28 23859.93363 23860.03004 -.09641 36 28 23902.05363 23902.06314 -.00951 37 28 23944.65063 23944.52648 .12415 38 28 23987.52863 23987.36788 .16075 39 28 24030.62134 24030.57878 .04256 40 28 24073.92134 24074.16367 -.24233 41 28 24117.39034 24118.10962 -.71928 43 28 24206.91634 24206.98167 -.06533 44 28 24251.70634 24251.86838 -.16204 45 28 24296.93634 24297.02922 -.09288 46 28 24342.43634 24342.44769 -.01135 47 28 24388.38359 24388.11052 .27307 48 28 24434.26359 24434.00138 .26221 49 28 24479.94359 24480.10352 -.15993 51 28 24573.90359 24572.84565 1.05794 52 28 24619.05359 24619.45047 -.39688 53 28 24663.11359 24666.18982 -3.07623 54 28 24718.01359 24713.05376 4.95983 27 29 23557.05184 23557.05119 .00065 28 29 23590.37184 23590.34097 .03087 29 29 23625.75184 23625.70080 .05104 30 29 23663.90584 23663.94754 -.04170 31 29 23703.33184 23703.37860 -.04676 32 29 23743.17184 23743.17282 -.00098 34 29 23824.09184 23824.10688 -.01504 35 29 23865.46184 23865.54238 -.08054 36 29 23907.53184 23907.53791 -.00607 37 29 23950.07184 23949.97516 .09668 25 30 23488.13634 23488.12339 .01295 26 30 23527.10634 23527.02500 .08134 27 30 23563.31755 23563.35368 -.03613 27 30 23563.38234 23563.35368 .02866 28 30 23596.92355 23596.91212 .01143 29 30 23631.87755 23631.84954 .02801 30 30 23669.77755 23669.81061 -.03306 31 30 23709.19755 23709.19127 .00628 31 30 23709.16234 23709.19127 -.02893 32 30 23749.00055 23749.00281 -.00226 33 30 23789.15055 23789.15461 -.00406 34 30 23829.82055 23829.86855 -.04800 35 30 23871.19755 23871.24576 -.04821 36 30 23913.18755 23913.19971 -.01216 37 30 23955.70755 23955.60868 .09887 38 30 23998.56634 23998.40049 .16585 39 30 24041.69634 24041.55283 .14351 39 30 24041.65634 24041.55283 .10351 40 30 24084.93634 24085.06996 -.13362 41 30 24128.33034 24128.94606 -.61572 43 30 24217.77634 24217.68256 .09378 44 30 24262.30634 24262.50074 -.19440 45 30 24307.47634 24307.59247 -.11613 46 30 24352.97634 24352.94166 .03468 47 30 24398.70634 24398.53303 .17331 47 31 24404.14619 24404.00926 .13693 48 31 24450.00619 24449.79003 .21616 49 31 24495.89619 24495.78528 .11091 50 31 24540.74619 24541.97000 -1.22381 51 31 24589.88619 24588.32289 1.56330 52 31 24635.05619 24634.82805 .22814 53 31 24679.97619 24681.46750 -1.49131 54 31 24718.81619 24728.23250 -9.41631 26 32 23538.71755 23538.62652 .09103 27 32 23576.26255 23576.19076 .07179 28 32 23610.66755 23610.68279 -.01524 29 32 23644.96255 23644.96852 -.00597 30 32 23682.19255 23682.19810 -.00555 31 32 23721.33255 23721.37894 -.04639 32 32 23761.18755 23761.21156 -.02401 33 32 23801.36755 23801.35669 .01086 34 32 23841.93755 23841.97461 -.03706 35 32 23883.19755 23883.22764 -.03009 36 32 23925.05755 23925.08540 -.02785 37 32 23967.49755 23967.42947 .06808 38 32 24010.32755 24010.16863 .15892 39 32 24053.41755 24053.26282 .15473 45 32 24318.70755 24318.87013 -.16258 46 32 24364.07755 24364.14617 -.06862 47 33 24415.49619 24415.49136 .00483 48 33 24461.32619 24461.19316 .13303 49 33 24507.31619 24507.11013 .20606 50 33 24552.81619 24553.21841 -.40222 51 33 24601.47619 24599.49820 1.97799 52 33 24646.46619 24645.93104 .53515 53 33 24691.69619 24692.49864 -.80245 54 33 24733.72619 24739.19193 -5.46574 28 34 23625.06625 23625.07252 -.00627 29 34 23659.19125 23659.19798 -.00673 30 34 23695.55025 23695.54050 .00975 31 34 23734.31225 23734.34130 -.02905 32 34 23774.11625 23774.14460 -.02835 33 34 23814.31625 23814.30575 .01050 34 34 23854.84625 23854.85323 -.00698 35 34 23895.91225 23895.97920 -.06695 36 34 23937.64625 23937.72325 -.07700 37 34 23979.99625 23979.98815 .00810 38 34 24022.76625 24022.66875 .09750 39 34 24065.83625 24065.70489 .13136 45 34 24330.66625 24330.86129 -.19504 46 34 24375.91625 24376.06031 -.14406 47 34 24421.59625 24421.49704 .09921 48 34 24467.33625 24467.15788 .17837 49 34 24513.30625 24513.03368 .27257 50 34 24558.93611 24559.10162 -.16551 51 34 24607.68611 24605.34287 2.34324 52 34 24652.38611 24651.73772 .64839 53 34 24697.77611 24698.26783 -.49172 28 36 23639.83625 23639.81904 .01721 29 36 23674.40625 23674.44387 -.03762 30 36 23709.93025 23709.93701 -.00676 31 36 23748.14625 23748.13201 .01424 32 36 23787.77625 23787.80371 -.02746 33 36 23828.00625 23827.98348 .02277 34 36 23868.49625 23868.49351 .00274 35 36 23909.47025 23909.50177 -.03152 36 36 23951.03625 23951.11749 -.08124 37 36 23993.26625 23993.28572 -.01947 38 36 24036.00124 24035.89797 .10327 39 36 24079.01625 24078.87457 .14168 40 36 24122.27625 24122.18662 .08963 41 36 24165.65124 24165.83514 -.18390 42 36 24208.95124 24209.81751 -.86627 44 36 24298.84124 24298.70401 .13723 45 36 24343.31825 24343.56483 -.24658 46 36 24388.40625 24388.68291 -.27666 47 36 24433.78625 24434.03704 -.25079 48 36 24479.70625 24479.61339 .09286 49 36 24525.66625 24525.40301 .26324 50 36 24571.48611 24571.38609 .10002 51 36 24619.72611 24617.54608 2.18003 52 36 24664.71611 24663.86113 .85498 53 36 24710.32611 24710.31307 .01304 28 37 23647.30423 23647.26645 .03778 29 37 23682.33423 23682.37523 -.04100 30 37 23717.55423 23717.55587 -.00164 31 37 23755.33423 23755.36337 -.02914 32 37 23794.88423 23794.91133 -.02710 33 37 23835.13423 23835.09056 .04367 34 37 23875.60423 23875.59405 .01018 32 38 23802.19124 23802.21075 -.01951 33 38 23842.35724 23842.37485 -.01761 34 38 23882.86755 23882.87807 -.01052 35 38 23923.75355 23923.79194 -.03839 36 38 23965.20124 23965.27249 -.07125 37 38 24007.24855 24007.32517 -.07662 38 38 24049.90124 24049.85482 .04642 39 38 24092.88355 24092.76726 .11629 40 38 24136.14355 24136.01303 .13052 41 38 24179.54355 24179.58446 -.04091 42 38 24222.88355 24223.48411 -.60056 43 38 24263.63355 24267.69820 -4.06465 44 38 24312.62355 24312.20280 .42075 45 38 24356.80024 24356.97935 -.17911 46 38 24401.62355 24402.01256 -.38901 47 38 24446.86355 24447.28078 -.41723 48 38 24492.73355 24492.76959 -.03604 49 38 24538.60355 24538.46849 .13506 50 38 24584.55355 24584.36139 .19216 51 38 24629.78355 24630.43431 -.65076 28 39 23662.39537 23662.25922 .13615 29 39 23698.60537 23698.64762 -.04225 29 39 23698.59423 23698.64762 -.05339 30 39 23733.60537 23733.63531 -.02994 31 39 23770.54537 23770.56435 -.01898 32 39 23809.67537 23809.70937 -.03400 33 39 23849.82537 23849.83638 -.01101 34 39 23890.36537 23890.34274 .02263 35 39 23931.22537 23931.22190 .00347 36 39 23972.57537 23972.63613 -.06076 37 39 24014.52537 24014.62450 -.09913 38 39 24057.12537 24057.10624 .01913 39 39 24100.14537 24099.98347 .16190 45 39 24363.75537 24363.95272 -.19735 46 39 24408.55537 24408.94200 -.38663 47 39 24453.68537 24454.16604 -.48067 48 39 24499.60537 24499.61005 -.00468 49 39 24545.31537 24545.26213 .05324 50 39 24591.27537 24591.10811 .16726 51 39 24636.95537 24637.13526 -.17989 52 39 24684.33537 24683.32054 1.01483 53 39 24730.09537 24729.64677 .44860 54 39 24775.55537 24776.09910 -.54373 56 39 24870.47537 24869.35008 1.12529 57 39 24914.96537 24916.13651 -1.17114 32 40 23817.38355 23817.41690 -.03335 33 40 23857.43355 23857.47655 -.04300 34 40 23897.98062 23897.98543 -.00481 35 40 23938.84355 23938.83913 .00442 36 40 23980.12955 23980.19044 -.06089 37 40 24022.04062 24022.11110 -.07048 38 40 24064.50355 24064.54002 -.03647 39 40 24107.47055 24107.37911 .09144 40 40 24150.71262 24150.55824 .15438 41 40 24194.08062 24194.05440 .02622 42 40 24237.47055 24237.87022 -.39967 43 40 24279.99762 24281.99717 -1.99955 44 40 24327.45055 24326.41421 1.03634 45 40 24371.03562 24371.10317 -.06755 45 40 24370.99355 24371.10317 -.10962 46 40 24415.68562 24416.04756 -.36194 47 40 24460.73562 24461.22658 -.49096 48 40 24506.79562 24506.62514 .17048 49 40 24552.25355 24552.22956 .02399 50 40 24598.16355 24598.02753 .13602 51 40 24644.06355 24644.00744 .05611 28 41 23677.62537 23677.39217 .23320 29 41 23715.18537 23715.20082 -.01545 30 41 23750.63537 23750.71187 -.07650 31 41 23786.79037 23786.83995 -.04958 32 41 23825.32037 23825.34534 -.02497 33 41 23865.28537 23865.29855 -.01318 34 41 23905.81537 23905.80388 .01149 35 41 23946.67537 23946.64106 .03431 36 41 23987.90537 23987.93487 -.02950 37 41 24029.70537 24029.78557 -.08020 38 41 24072.14537 24072.15665 -.01128 39 41 24115.06537 24114.95398 .11139 45 41 24378.44537 24378.43043 .01494 46 41 24422.96537 24423.32899 -.36362 47 41 24467.25537 24468.46216 -1.20679 48 41 24514.48537 24513.81459 .67078 49 41 24559.32537 24559.37063 -.04526 50 41 24605.21537 24605.11961 .09576 51 41 24651.17537 24651.05083 .12454 52 41 24698.29537 24697.14259 1.15278 53 41 24743.94537 24743.37878 .56659 54 41 24789.73537 24789.74247 -.00710 56 41 24884.74537 24882.81944 1.92593 57 41 24929.24537 24929.52261 -.27724 32 42 23833.45562 23833.50871 -.05309 33 42 23873.26562 23873.30762 -.04200 34 42 23913.78562 23913.79665 -.01103 35 42 23954.63562 23954.62472 .01090 36 42 23995.81562 23995.86831 -.05269 37 42 24037.58562 24037.64834 -.06272 38 42 24079.90562 24079.95676 -.05114 39 42 24122.74562 24122.70805 .03757 40 42 24165.94562 24165.81669 .12893 41 42 24209.34562 24209.23965 .10597 42 42 24252.77562 24252.97221 -.19659 43 42 24295.82562 24297.00963 -1.18401 44 42 24343.76562 24341.33597 2.42965 44 42 24343.78562 24341.33597 2.44965 45 42 24386.17562 24385.93419 .24143 46 42 24430.51562 24430.78602 -.27040 47 42 24475.30562 24475.87250 -.56688 33 43 23881.49088 23881.51142 -.02054 34 43 23921.97088 23921.96348 .00740 35 43 23962.93088 23962.78697 .14391 36 43 24003.95088 24003.98905 -.03817 37 43 24045.65088 24045.69961 -.04873 38 43 24087.90088 24087.94102 -.04014 39 43 24130.64088 24130.64152 -.00064 40 43 24173.80588 24173.71187 .09401 41 43 24217.22088 24217.09857 .12231 42 43 24260.67588 24260.79015 -.11427 43 43 24303.88588 24304.78238 -.89650 44 43 24353.11088 24349.06240 4.04848 45 43 24393.98088 24393.61411 .36677 46 43 24438.14088 24438.41837 -.27749 47 43 24482.81088 24483.45732 -.64644 48 43 24527.33088 24528.71533 -1.38445 49 43 24574.10088 24574.17285 -.07197 50 43 24619.78088 24619.82135 -.04047 51 43 24665.74088 24665.65117 .08971 52 43 24710.24088 24711.64378 -1.40290 33 45 23898.53088 23898.54651 -.01563 34 45 23938.84088 23938.82674 .01414 35 45 23979.64088 23979.63576 .00512 36 45 24020.81088 24020.78264 .02824 37 45 24062.33088 24062.36631 -.03543 38 45 24104.40088 24104.46481 -.06393 39 45 24147.02588 24147.04828 -.02240 40 45 24190.09088 24190.03221 .05867 41 45 24233.47088 24233.34494 .12594 42 45 24276.97588 24276.95617 .01971 43 45 24320.37588 24320.85828 -.48240 44 45 24361.42088 24365.04429 -3.62341 45 45 24410.43088 24409.50091 .92997 46 45 24454.14088 24454.20775 -.06687 47 45 24498.55088 24499.14917 -.59829 48 45 24543.24088 24544.30953 -1.06865 49 45 24589.80088 24589.66665 .13423 50 45 24635.07088 24635.21210 -.14122 51 45 24680.94088 24680.93595 .00493 52 45 24726.89088 24726.82406 .06682 30 46 23795.60274 23795.60062 .00212 31 46 23832.03274 23832.17165 -.13891 32 46 23868.67274 23868.79139 -.11865 33 46 23907.34274 23907.40527 -.06253 34 46 23947.49274 23947.53236 -.03962 35 46 23988.33774 23988.31825 .01949 36 46 24029.46274 24029.44938 .01336 37 46 24070.95774 24070.97969 -.02195 38 46 24112.92774 24113.00537 -.07763 39 46 24155.47274 24155.52285 -.05011 40 46 24198.50274 24198.45718 .04556 41 46 24241.89274 24241.73087 .16187 42 46 24285.40274 24285.30252 .10022 47 46 24506.79274 24507.25556 -.46282 48 46 24551.36274 24552.36574 -1.00300 50 46 24643.04274 24643.16523 -.12249 51 46 24688.78574 24688.83474 -.04900 52 46 24734.73274 24734.66881 .06393 53 46 24781.04274 24780.65507 .38767 54 46 24827.16274 24826.77721 .38553 55 46 24873.09274 24873.02396 .06878 56 46 24915.94274 24919.38589 -3.44315 57 46 24966.97274 24965.86225 1.11049 58 46 25012.10274 25012.44992 -.34718 59 46 25055.81274 25059.14557 -3.33283 30 48 23813.82274 23813.68467 .13807 31 48 23851.38274 23851.49649 -.11375 32 48 23887.92274 23888.06634 -.14360 33 48 23925.80274 23925.88170 -.07896 34 48 23965.49774 23965.53400 -.03626 35 48 24006.21274 24006.19934 .01340 36 48 24047.35274 24047.30616 .04658 37 48 24088.78274 24088.75644 .02630 38 48 24130.60774 24130.64399 -.03625 39 48 24172.93274 24173.01808 -.08534 40 48 24215.81274 24215.83800 -.02526 41 48 24259.14274 24259.02540 .11734 42 48 24302.64274 24302.51730 .12544 47 48 24523.66274 24523.98740 -.32466 48 48 24568.11274 24568.99439 -.88165 50 48 24659.52274 24659.58516 -.06242 51 48 24704.95774 24705.14420 -.18646 52 48 24750.82274 24750.86721 -.04447 53 48 24796.94274 24796.74344 .19930 54 48 24843.05274 24842.75996 .29278 55 48 24889.13274 24888.90490 .22784 56 48 24934.50274 24935.16795 -.66521 57 48 24983.09274 24981.54721 1.54553 58 48 25028.23274 25028.03936 .19338 59 48 25073.06274 25074.64331 -1.58057 35 49 24015.41431 24015.40394 .01037 36 49 24056.51431 24056.49064 .02367 37 49 24097.95431 24097.91394 .04037 38 49 24139.70431 24139.74055 -.03624 39 49 24181.96431 24182.04008 -.07577 40 49 24224.75431 24224.79501 -.04070 41 49 24267.98031 24267.93343 .04688 42 49 24311.51031 24311.38395 .12636 43 49 24355.10931 24355.11151 -.00220 44 49 24398.37031 24399.10912 -.73881 45 49 24448.05431 24443.36909 4.68522 46 49 24488.58431 24487.87430 .71001 47 49 24532.43431 24532.61202 -.17771 48 49 24576.73431 24577.56602 -.83171 49 49 24620.22431 24622.71681 -2.49250 50 49 24668.11431 24668.05103 .06328 51 49 24713.34431 24713.55429 -.20998 52 49 24759.10315 24759.22056 -.11741 52 49 24759.10431 24759.22056 -.11625 53 49 24805.08715 24805.03995 .04720 54 49 24851.21415 24851.00162 .21253 55 49 24897.32431 24897.09377 .23054 56 49 24943.08415 24943.30610 -.22195 58 49 25036.43415 25036.07871 .35544 59 49 25081.57915 25082.63514 -1.05599 61 49 25176.39915 25176.06844 .33071 35 51 24034.38431 24034.37608 .00823 36 51 24075.42431 24075.36647 .05784 37 51 24116.81431 24116.74997 .06434 38 51 24158.45431 24158.47924 -.02493 39 51 24200.60431 24200.63394 -.02963 40 51 24243.18431 24243.24612 -.06181 41 51 24286.26031 24286.27150 -.01119 42 51 24329.71431 24329.63227 .08204 43 51 24373.38931 24373.27454 .11477 44 51 24416.90431 24417.18045 -.27614 45 51 24458.31431 24461.34094 -3.02663 46 51 24507.12431 24505.74352 1.38079 47 51 24550.60431 24550.37615 .22816 48 51 24594.64431 24595.22182 -.57751 49 51 24638.64431 24640.26584 -1.62153 50 51 24686.41431 24685.49193 .92238 51 51 24730.67431 24730.88318 -.20887 52 51 24776.14315 24776.43442 -.29127 53 51 24821.97115 24822.13729 -.16614 54 51 24868.01231 24867.98536 .02695 55 51 24914.11915 24913.96797 .15118 56 51 24960.15415 24960.07595 .07820 56 51 24960.14431 24960.07595 .06836 58 51 25053.20315 25052.64636 .55679 59 51 25098.73915 25099.10480 -.36565 61 51 25193.79915 25192.35245 1.44670 50 55 24721.36730 24722.39380 -1.02650 51 55 24767.00730 24767.55993 -.55263 52 55 24812.81730 24812.87880 -.06150 38 56 24208.45143 24208.36230 .08913 39 56 24250.30143 24250.26651 .03492 40 56 24292.51143 24292.52575 -.01432 41 56 24335.13143 24335.19032 -.05889 42 56 24378.25143 24378.25072 .00071 43 56 24421.70143 24421.64954 .05189 44 56 24465.40143 24465.32640 .07503 45 56 24509.08543 24509.24452 -.15909 46 56 24550.67143 24553.39262 -2.72119 47 56 24599.28143 24597.75863 1.52280 48 56 24642.69143 24642.32761 .36382 49 56 24686.55143 24687.09233 -.54090 50 56 24729.91543 24732.03667 -2.12124 51 56 24778.82143 24777.14583 1.67560 52 56 24822.19143 24822.40657 -.21514 54 56 24912.53143 24913.35993 -.82850 50 57 24741.98730 24741.84533 .14197 51 57 24787.01730 24786.89700 .12030 52 57 24832.76730 24832.09956 .66774 38 58 24229.54143 24229.47703 .06440 39 58 24271.38143 24271.31852 .06291 40 58 24313.51143 24313.47858 .03285 41 58 24355.96143 24355.99777 -.03634 42 58 24398.86143 24398.90716 -.04573 43 58 24442.19143 24442.17955 .01188 44 58 24485.80143 24485.75214 .04929 45 58 24529.60543 24529.57393 .03150 46 58 24572.94043 24573.62254 -.68211 47 58 24620.58143 24617.88244 2.69899 48 58 24663.16143 24662.34204 .81939 49 58 24706.91143 24706.99207 -.08064 50 58 24750.53643 24751.81917 -1.28274 51 58 24797.33143 24796.81270 .51873 52 58 24842.30143 24841.95699 .34444 53 58 24886.71143 24887.24421 -.53278 54 58 24931.73143 24932.67061 -.93918 34 61 24103.69520 24103.55065 .14455 35 61 24142.69520 24142.78534 -.09014 36 61 24181.52520 24181.66232 -.13712 37 61 24221.42520 24221.49028 -.06508 38 61 24262.44520 24262.45186 -.00666 39 61 24304.18520 24304.11500 .07020 40 61 24346.23520 24346.16345 .07175 41 61 24388.55520 24388.51358 .04162 42 61 24431.15520 24431.19966 -.04446 43 61 24474.16520 24474.24918 -.08398 45 61 24561.34520 24561.29574 .04946 34 63 24126.31520 24125.97786 .33734 35 63 24166.36520 24166.32912 .03608 36 63 24205.47520 24205.57324 -.09804 37 63 24244.84520 24244.97169 -.12649 38 63 24285.37520 24285.42128 -.04608 39 63 24326.86520 24326.81475 .05045 40 63 24368.85520 24368.75537 .09983 42 63 24453.60520 24453.58843 .01677 43 63 24496.41520 24496.48454 -.06934 44 63 24539.64520 24539.71904 -.07384 45 63 24583.25520 24583.25747 -.00227 46 63 24627.11520 24627.04559 .06961 42 64 24465.09133 24465.03283 .05850 43 64 24507.80133 24507.85769 -.05636 44 64 24550.89133 24551.01430 -.12297 45 64 24594.40133 24594.48306 -.08173 46 64 24638.22133 24638.21160 .00973 47 64 24682.12133 24682.15666 -.03533 37 66 24281.72366 24281.75638 -.03272 38 66 24321.54366 24321.56822 -.02456 39 66 24362.32866 24362.28876 .03990 40 66 24403.99366 24403.86796 .12570 41 66 24446.11366 24445.97449 .13917 42 66 24488.53366 24488.40229 .13137 43 66 24531.13066 24531.10457 .02609 44 66 24574.07133 24574.10900 -.03767 45 66 24617.34366 24617.42660 -.08294 46 66 24660.99133 24661.02312 -.03179 47 66 24704.91866 24704.85446 .06420 48 66 24748.55366 24748.88394 -.33028 49 66 24794.62366 24793.08823 1.53543 50 66 24838.28366 24837.45502 .82864 51 66 24882.14366 24881.97352 .17014 52 66 24925.20366 24926.64241 -1.43875 53 66 24976.74366 24971.45685 5.28681 54 66 25017.10366 25016.41235 .69131 55 66 25060.72366 25061.50333 -.77967 56 66 25104.47366 25106.72545 -2.25179 38 68 24346.70366 24346.72183 -.01817 39 68 24386.98866 24387.01142 -.02276 40 68 24428.23866 24428.18079 .05787 41 68 24470.22366 24470.06946 .15420 42 68 24512.56366 24512.39149 .17217 43 68 24555.11366 24554.99579 .11787 44 68 24597.89866 24597.86732 .03134 45 68 24640.94366 24641.02890 -.08524 46 68 24684.37866 24684.47702 -.09836 47 68 24728.14366 24728.18050 -.03684 48 68 24772.12866 24772.09356 .03510 49 68 24813.12366 24816.18732 -3.06366 50 68 24861.42366 24860.44389 .97977 51 68 24905.40366 24904.84964 .55402 52 68 24949.10366 24949.40138 -.29772 53 68 24990.10366 24994.09667 -3.99301 54 68 25040.99366 25038.93533 2.05833 55 68 25083.86366 25083.91116 -.04750 56 68 25127.46366 25129.01951 -1.55585 38 69 24359.52516 24359.51555 .00961 39 69 24399.66516 24399.69861 -.03345 40 69 24440.67516 24440.64097 .03419 41 69 24482.45516 24482.37164 .08352 42 69 24524.73516 24524.61634 .11882 43 69 24567.30516 24567.17353 .13163 44 69 24610.00516 24609.98858 .01658 45 69 24652.97516 24653.07595 -.10079 38 71 24385.08516 24385.27145 -.18629 39 71 24425.59516 24425.61303 -.01787 40 71 24466.19516 24466.19844 -.00328 41 71 24507.59516 24507.53468 .06048 42 71 24549.67516 24549.54385 .13131 43 71 24592.13516 24591.98121 .15395 44 71 24634.79516 24634.69604 .09912 45 71 24677.65516 24677.65214 .00302 46 71 24720.72516 24720.86898 -.14382 44 74 24673.06222 24672.87465 .18757 45 74 24715.82222 24715.66989 .15233 46 74 24758.72222 24758.69016 .03206 47 74 24801.86222 24801.94071 -.07849 49 74 24889.01222 24889.14103 -.12881 50 74 24933.00222 24933.04298 -.04076 51 74 24977.62222 24977.11364 .50858 52 74 25021.77222 25021.33395 .43827 53 74 25065.93222 25065.69509 .23713 54 74 25109.48222 25110.19188 -.70966 44 76 24699.26222 24699.07890 .18332 46 76 24784.77222 24784.65790 .11432 47 76 24827.77222 24827.77578 -.00356 48 76 24871.00222 24871.11374 -.11152 49 76 24914.49222 24914.67351 -.18129 50 76 24958.27222 24958.43855 -.16633 51 76 25002.23222 25002.38493 -.15271 52 76 25046.70222 25046.49286 .20936 53 76 25091.00222 25090.74814 .25408 54 76 25135.06222 25135.13944 -.07722 57 76 25269.05222 25269.11964 -.06742 ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Table 2. Points defining the IPA potential energy curve for the 4^1\Sigma^+ state of KLi. R[A] U[cm-1] 2.0 37925.8615 2.5 30275.5394 2.9 26473.9939 3.2 24268.6924 3.4 23656.6055 3.6 23403.9712 3.8 23345.9391 4.0 23331.8632 4.2 23203.7554 4.6 23052.5955 5.0 22891.3750 5.6 22787.8222 6.2 22595.6550 6.8 22401.5046 7.4 22319.0823 7.8 22379.3741 8.2 22520.4906 8.5 22755.9624 9.0 23101.6559 9.5 23573.2768 10.0 24089.2810 10.5 24600.3837 11.0 25101.1631 11.5 25590.7476 12.0 25954.5598 12.5 26237.9416 13.0 26441.1669 14.0 26716.6458 15.0 26932.4361 16.0 27093.6100 17.0 27192.2928 19.0 27240.0055 21.0 27241.6478