Title of the corresponding paper: 
Experimental investigation of electronic states of LiCs dissociating to Li($2^2$S) 
and Cs($5^2$D) atoms

authors:

A. Grochola (a), J. Szczepkowski (b), W. Jastrzebski (b), and P. Kowalczyk (a)
(a) Institute of Experimental Physics, Faculty of Physics, University of Warsaw, ul. Hoza 69, 
00-681 Warszawa, Poland
(b) Institute of Physics, Polish Academy of Sciences, Al.Lotnikow 32/46, 02-668 Warszawa, Poland

contact address: Anna.Grochola@fuw.edu.pl

Supplementary material

1. The (4)0^+ state

a) Observed spectral lines in the (4)0^+ <-- X band system

v'     J'   v"    J"  wave number [cm-1]
3	18	0	19	17068.02
3	20	0	19	17078.13
4	18	0	19	17179.73
4	20	0	19	17189.76
5	18	0	19	17289.98
5	20	0	19	17300.02
6	18	0	19	17398.79
6	20	0	19	17408.74
7	18	0	19	17505.71
7	20	0	19	17515.63
8	18	0	19	17609.86
8	20	0	19	17619.71
8	22	0	23	17598.53
8	24	0	23	17610.33
9	22	0	23	17697.75
7	24	0	25	17488.16
7	26	0	25	17501.02
8	24	0	25	17592.09
8	26	0	25	17605.02
3	27	0	28	17041.02
3	29	0	28	17055.68
4	27	0	28	17152.34
4	29	0	28	17167.00
5	27	0	28	17262.39
5	29	0	28	17276.91
6	27	0	28	17370.88
6	29	0	28	17385.37
7	27	0	28	17477.66
7	29	0	28	17492.15
8	27	0	28	17581.52
8	29	0	28	17595.87
8	28	0	29	17577.71
8	30	0	29	17592.68
9	28	0	29	17676.87
9	30	0	29	17691.54
3	29	0	30	17033.72
3	31	0	30	17049.43
4	29	0	30	17144.97
4	31	0	30	17160.63
5	29	0	30	17254.90
5	31	0	30	17270.50
6	29	0	30	17363.36
6	31	0	30	17378.79
7	29	0	30	17470.23
7	31	0	30	17485.29
8	29	0	30	17573.92
8	31	0	30	17589.25
9	29	0	30	17672.98
9	31	0	30	17688.21
8	30	0	31	17569.93
8	32	0	31	17585.76
9	30	0	31	17668.90
9	32	0	31	17684.61
8	31	0	32	17565.77
8	35	0	34	17574.53
9	33	0	34	17655.93
9	35	0	34	17672.78
3	34	0	35	17013.63
3	36	0	35	17031.82
4	34	0	35	17124.63
4	36	0	35	17142.80
5	34	0	35	17234.40
5	36	0	35	17252.40
6	34	0	35	17342.64
6	36	0	35	17360.49
7	34	0	35	17448.94
7	36	0	35	17466.77
8	34	0	35	17552.73
8	36	0	35	17570.50
9	34	0	35	17651.50
9	36	0	35	17669.11
8	36	0	37	17543.89
8	38	0	37	17562.19
8	38	0	39	17533.69
8	40	0	39	17553.33
9	38	0	39	17632.13
9	40	0	39	17651.67
8	39	0	40	17528.62
8	41	0	40	17548.79
9	39	0	40	17627.10
9	41	0	40	17647.10
4	42	0	43	17086.10
4	44	0	43	17108.14
5	42	0	43	17195.37
5	44	0	43	17217.25
6	42	0	43	17303.14
6	44	0	43	17324.94
7	42	0	43	17409.18
7	44	0	43	17430.80
8	42	0	43	17512.64
8	44	0	43	17534.20
3	44	0	45	16964.92
3	46	0	45	16988.07
4	44	0	45	17075.32
4	46	0	45	17098.33
5	44	0	45	17184.48
6	44	0	45	17292.15
6	46	0	45	17314.86
7	44	0	45	17397.97
7	46	0	45	17420.59
8	44	0	45	17501.40
8	46	0	45	17523.93
9	44	0	45	17599.38
9	46	0	45	17621.72
9	45	0	46	17593.55
9	47	0	46	17616.27
3	46	0	47	16953.85
3	48	0	47	16977.95
4	48	0	47	17088.08
5	46	0	47	17173.08
5	48	0	47	17196.86
6	46	0	47	17280.61
6	48	0	47	17304.32
7	46	0	47	17386.37
7	48	0	47	17409.90
8	46	0	47	17489.70
8	48	0	47	17513.24
4	49	0	50	17046.41
4	51	0	50	17071.79
5	49	0	50	17155.18
5	51	0	50	17180.43
6	49	0	50	17262.50
6	51	0	50	17287.56
7	49	0	50	17368.01
7	51	0	50	17392.91
8	49	0	50	17471.38
8	51	0	50	17496.45
9	49	0	50	17568.78
9	51	0	50	17593.39
8	51	0	52	17458.53
4	52	0	53	17027.74
4	54	0	53	17054.53
5	52	0	53	17136.22
5	54	0	53	17162.88
6	52	0	53	17243.30
6	54	0	53	17269.80
7	52	0	53	17348.59
8	52	0	53	17452.10
9	52	0	53	17548.76
9	54	0	53	17574.73
1	25	1	26	16639.39
1	27	1	26	16653.22
2	25	1	26	16753.29
2	27	1	26	16767.00
0	32	1	33	16500.27
0	34	1	33	16517.80
1	32	1	33	16614.85
1	34	1	33	16632.28
2	32	1	33	16728.34
2	34	1	33	16745.66
0	41	1	42	16461.43
0	43	1	42	16483.53
1	41	1	42	16575.45
1	43	1	42	16597.42
2	41	1	42	16688.45
3	41	1	42	16800.23
3	43	1	42	16821.95
7	42	1	43	17228.82
7	44	1	43	17250.49
8	44	1	43	17353.88
9	42	1	43	17430.46
9	44	1	43	17451.88
10	42	1	43	17521.41
10	44	1	43	17542.47
7	44	1	45	17217.92
7	46	1	45	17240.51
8	44	1	45	17321.93
8	46	1	45	17343.86
9	44	1	45	17419.34
9	46	1	45	17441.64
10	44	1	45	17509.92
10	46	1	45	17531.89
7	53	1	52	17201.82
8	51	1	52	17279.38
9	51	1	52	17376.30
9	53	1	52	17401.85
10	51	1	52	17465.68
10	53	1	52	17490.79
11	51	1	52	17550.54
11	53	1	52	17575.27
1	52	1	53	16515.70
1	54	1	53	16543.04
2	52	1	53	16627.84
2	54	1	53	16654.97
3	52	1	53	16738.85
3	54	1	53	16765.82
9	53	1	54	17362.99
9	55	1	54	17389.43
10	53	1	54	17451.94
10	55	1	54	17477.88
11	53	1	54	17536.48
11	55	1	54	17561.97
1	56	1	57	16490.84
1	58	1	57	16520.06
2	56	1	57	16602.62
2	58	1	57	16631.72
3	56	1	57	16713.25
3	58	1	57	16742.10
8	58	1	59	17230.05
8	60	1	59	17258.91
9	58	1	59	17327.39
9	60	1	59	17355.99
10	58	1	59	17415.25
10	60	1	59	17443.40
11	58	1	59	17498.70
11	60	1	59	17526.42
6	18	2	19	17036.38
6	20	2	19	17046.27
7	18	2	19	17143.25
7	20	2	19	17153.19
8	18	2	19	17247.41
8	20	2	19	17257.25
9	18	2	19	17346.84
9	20	2	19	17356.63
7	19	2	20	17140.75
7	21	2	20	17151.14
8	19	2	20	17244.86
8	21	2	20	17255.24
7	23	2	24	17129.38
7	25	2	24	17141.81
1	24	2	25	16462.67
1	26	2	25	16475.98
2	24	2	25	16576.55
2	26	2	25	16589.84
3	24	2	25	16689.30
3	26	2	25	16702.46
6	25	2	26	17016.29
6	27	2	26	17029.77
7	25	2	26	17123.09
7	27	2	26	17136.54
8	25	2	26	17227.05
8	27	2	26	17240.38
9	25	2	26	17326.24
9	27	2	26	17339.51
1	31	2	32	16439.30
1	33	2	32	16456.26
2	31	2	32	16552.90
2	33	2	32	16569.70
3	31	2	32	16665.35
3	33	2	32	16681.99
6	31	2	32	16994.70
6	33	2	32	17011.17
7	33	2	32	17117.57
8	31	2	32	17205.12
8	33	2	32	17221.38
9	31	2	32	17304.03
9	33	2	32	17320.24
6	35	2	36	16978.12
6	37	2	36	16996.50
7	35	2	36	17084.44
7	37	2	36	17102.73
8	35	2	36	17188.18
8	37	2	36	17206.42
2	36	2	37	16532.84
2	38	2	37	16552.16
3	36	2	37	16644.94
3	38	2	37	16664.15
3	41	2	42	16622.03
6	41	2	42	16949.75
6	43	2	42	16971.01
7	41	2	42	17055.78
7	43	2	42	17076.94
8	41	2	42	17159.32
8	43	2	42	17180.46
9	41	2	42	17257.62
6	46	2	47	16923.05
7	46	2	47	17028.77
7	48	2	47	17052.31
8	46	2	47	17132.16
8	48	2	47	17155.65
9	46	2	47	17229.91
9	48	2	47	17253.18
6	50	2	49	16936.19
7	48	2	49	17017.14
7	50	2	49	17041.64
8	48	2	49	17120.48
8	50	2	49	17144.96
7	51	2	52	16998.89
7	53	2	52	17024.72
8	51	2	52	17102.28
8	53	2	52	17127.19
9	51	2	52	17199.24
9	53	2	52	17224.75
11	53	2	52	17398.23
12	53	2	52	17480.03
13	51	2	52	17539.66
13	53	2	52	17563.87
1	51	2	52	16344.60
1	53	2	52	16371.39
2	51	2	52	16456.69
2	53	2	52	16483.48
3	51	2	52	16567.94
3	53	2	52	16594.47
4	51	2	52	16677.84
4	53	2	52	16704.15
6	51	2	52	16893.54
6	53	2	52	16919.55
7	51	2	52	16998.89
7	53	2	52	17024.78
9	51	2	52	17199.24
9	53	2	52	17224.78
6	54	2	55	16874.52
6	56	2	55	16901.83
7	54	2	55	16979.59
7	56	2	55	17006.84
9	54	2	55	17179.46
9	56	2	55	17206.21
11	54	2	55	17352.20
11	56	2	55	17378.47
12	54	2	55	17435.19
12	56	2	55	17460.82
13	54	2	55	17517.98
13	56	2	55	17543.48
0	80	2	81	16024.95
1	80	2	81	16135.08
1	82	2	81	16175.15
2	80	2	81	16244.12
2	82	2	81	16283.90
3	82	2	81	16391.50
4	80	2	81	16458.65
4	82	2	81	16497.87
0	18	3	19	16185.25
0	20	3	19	16195.56
1	18	3	19	16300.44
1	20	3	19	16310.68
2	18	3	19	16414.49
2	20	3	19	16424.68
0	23	3	24	16172.72
0	25	3	24	16185.63
1	23	3	24	16287.72
1	25	3	24	16300.56
2	23	3	24	16401.58
2	25	3	24	16414.38
3	23	3	24	16514.44
3	25	3	24	16527.03
0	28	3	29	16157.64
0	30	3	29	16173.16
1	28	3	29	16272.48
1	30	3	29	16287.87
2	28	3	29	16386.16
2	30	3	29	16401.45
3	28	3	29	16498.70
3	30	3	29	16513.93
0	37	3	38	16124.27
0	39	3	38	16144.33
1	37	3	38	16238.53
1	39	3	38	16258.52
2	37	3	38	16351.76
2	39	3	38	16371.61
9	41	3	42	17081.29
9	43	3	42	17102.19
10	41	3	42	17172.39
10	43	3	42	17193.01
0	47	3	48	16077.62
0	49	3	48	16102.66
1	47	3	48	16191.24
1	49	3	48	16216.13
2	47	3	48	16303.79
2	49	3	48	16328.54
0	53	3	54	16044.92
0	55	3	54	16072.92
1	53	3	54	16158.07
1	55	3	54	16185.90
2	53	3	54	16270.07
2	55	3	54	16297.75
3	53	3	54	16381.05
3	55	3	54	16408.51
9	53	3	54	17011.43
9	55	3	54	17037.84
10	53	3	54	17100.34
10	55	3	54	17126.32
11	53	3	54	17184.85
11	55	3	54	17210.39
0	58	3	59	16015.04
0	60	3	59	16045.41
1	58	3	59	16127.69
1	60	3	59	16157.88
2	58	3	59	16239.28
2	60	3	59	16269.30
3	58	3	59	16349.77
3	60	3	59	16379.59
10	58	3	59	17065.17
10	60	3	59	17093.34
11	58	3	59	17148.64
11	60	3	59	17176.35
0	24	4	25	15994.09
1	24	4	25	16109.11
1	26	4	25	16122.44

b) Dunham coefficients for the (4)0^+ state (relevant for v'<10)

      VALUE [cm-1]        ERROR [cm-1]         

   .1678645673D+05     .7274798501D-01       Y ( 0, 0) 
   .1150078486D+03     .1114616643D+00       Y ( 1, 0) 
   .5618053733D+00     .6416013017D-01       Y ( 2, 0) 
  -.3395129823D+00     .1562014811D-01       Y ( 3, 0) 
   .4439827828D-01     .1677476928D-02       Y ( 4, 0) 
  -.2209175093D-02     .6571249915D-04       Y ( 5, 0) 
   .1324529806D+00     .3460810230D-04       Y ( 0, 1) 
  -.7009579157D-03     .1201994170D-04       Y ( 1, 1) 
   .6058700447D-05     .9063916905D-06       Y ( 2, 1) 
  -.5890706942D-06     .5577867326D-08       Y ( 0, 2) 
  -.3032598402D-07     .1653319791D-08       Y ( 1, 2) 

   ROOT FROM M. QUAD. DEV. =     .111718 cm-1

c) RKR potential for the (4)0^+ state (for v'=0 - 13)

         R[A]         V[cm-1]
      3.3000000   19017.3580281
      3.3500000   18768.0900761
      3.4000000   18541.5588080
      3.4500000   18334.7428383
      3.5000000   18146.1699807
      3.5500000   17974.2051114
      3.6000000   17817.3848127
      3.6500000   17674.3781639
      3.7000000   17543.9508347
      3.7500000   17425.0692322
      3.8000000   17316.4040147
      3.8500000   17219.9955859
      3.9000000   17136.3388652
      3.9500000   17064.1739066
      4.0000000   17002.0242343
      4.0500000   16948.6015347
      4.1000000   16903.0322213
      4.1500000   16864.8464775
      4.2000000   16833.8996128
      4.2500000   16810.2581726
      4.3000000   16794.0665091
      4.3500000   16785.4195397
      4.4000000   16784.2371920
      4.4500000   16790.2621574
      4.5000000   16803.0159850
      4.5500000   16821.9186496
      4.6000000   16846.3326949
      4.6500000   16875.6746760
      4.7000000   16909.4650283
      4.7500000   16947.3570962
      4.8000000   16989.1375407
      4.8500000   17034.7015072
      4.9000000   17084.0106482
      4.9500000   17137.0219665
      5.0000000   17193.6103265
      5.0500000   17253.5088109
      5.1000000   17316.1240168
      5.1500000   17380.7339187
      5.2000000   17446.4543724
      5.2500000   17511.8665885
      5.3000000   17575.2874969
      5.3500000   17635.7467113
      5.4000000   17692.7095626
      5.4500000   17746.1164650
      5.5000000   17796.1003108
      5.5500000   17842.9888259
      5.6000000   17887.2691996
      5.6500000   17929.6492970
      5.7000000   17970.6862235
      5.7500000   18010.5425413
      5.8000000   18049.9705612
      5.8500000   18092.5102425
      5.9000000   18141.4256628

2. The (5)1 state

a) Observed spectral lines in the (5)1 <-- X band system

v'     J'   v"    J"  wave number [cm-1]
1	18	0	19	17404.25
1	20	0	19	17414.95
2	18	0	19	17501.29
2	20	0	19	17511.80
3	18	0	19	17595.83
3	20	0	19	17606.13
4	18	0	19	17687.85
4	20	0	19	17698.00
5	18	0	19	17777.62
5	20	0	19	17787.52
6	18	0	19	17865.17
6	20	0	19	17875.01
7	18	0	19	17950.76
7	20	0	19	17960.44
8	18	0	19	18034.57
8	20	0	19	18044.11
9	18	0	19	18116.86
9	20	0	19	18126.26
3	23	0	23	17591.11
3	24	0	23	17597.88
4	22	0	23	17677.15
4	23	0	23	17682.71
4	24	0	23	17689.34
5	22	0	23	17766.40
5	23	0	23	17771.94
5	24	0	23	17778.51
6	22	0	23	17853.73
6	23	0	23	17859.16
6	24	0	23	17865.53
7	23	0	23	17944.34
8	23	0	23	18027.73
2	25	0	25	17491.90
3	24	0	25	17579.67
3	25	0	25	17585.73
3	26	0	25	17593.11
4	24	0	25	17671.15
4	25	0	25	17677.14
4	26	0	25	17684.39
5	24	0	25	17760.30
5	25	0	25	17766.22
5	26	0	25	17773.32
6	24	0	25	17847.34
6	25	0	25	17853.25
6	26	0	25	17860.15
7	24	0	25	17932.42
7	25	0	25	17938.24
7	26	0	25	17945.02
8	24	0	25	18015.79
8	25	0	25	18021.46
8	26	0	25	18028.20
9	24	0	25	18097.68
9	25	0	25	18103.06
9	26	0	25	18109.97
10	25	0	25	18183.05
3	27	0	28	17570.01
3	28	0	28	17576.71
3	29	0	28	17584.97
4	27	0	28	17661.10
4	28	0	28	17667.82
4	29	0	28	17675.88
5	27	0	28	17749.91
5	28	0	28	17756.53
5	29	0	28	17764.43
6	27	0	28	17836.65
6	28	0	28	17843.14
6	29	0	28	17850.94
7	27	0	28	17921.44
7	28	0	28	17927.87
7	29	0	28	17935.48
8	27	0	28	18004.53
8	28	0	28	18010.79
8	29	0	28	18018.31
9	27	0	28	18086.20
9	28	0	28	18092.12
9	29	0	28	18100.05
10	27	0	28	18165.75
10	28	0	28	18171.83
10	29	0	28	18179.25
3	28	0	29	17566.55
3	29	0	29	17573.50
3	30	0	29	17582.04
4	28	0	29	17657.54
4	29	0	29	17664.44
4	30	0	29	17672.86
5	28	0	29	17746.26
5	29	0	29	17753.07
5	30	0	29	17761.27
6	28	0	29	17832.86
6	29	0	29	17839.63
6	30	0	29	17847.64
7	28	0	29	17917.48
7	29	0	29	17924.18
7	30	0	29	17932.08
8	28	0	29	18000.53
8	29	0	29	18007.02
8	30	0	29	18014.80
9	28	0	29	18082.24
9	29	0	29	18088.24
10	29	0	29	18167.80
11	29	0	29	18246.50
12	29	0	29	18324.15
13	29	0	29	18400.95
0	30	0	30	17282.89
1	29	0	30	17374.00
1	30	0	30	17381.23
1	31	0	30	17390.60
2	30	0	30	17476.97
3	29	0	30	17563.05
3	30	0	30	17570.21
3	31	0	30	17579.10
3	29	0	30	17563.11
4	29	0	30	17653.97
4	31	0	30	17669.74
5	29	0	30	17742.54
5	31	0	30	17758.03
6	29	0	30	17829.03
6	31	0	30	17844.27
7	29	0	30	17913.58
7	31	0	30	17928.55
8	29	0	30	17996.42
8	31	0	30	18011.19
10	30	0	30	18163.74
11	30	0	30	18242.35
3	30	0	31	17559.40
3	31	0	31	17566.76
3	32	0	31	17575.93
4	30	0	31	17650.11
4	31	0	31	17657.48
4	32	0	31	17666.40
5	30	0	31	17738.61
5	31	0	31	17745.86
5	32	0	31	17754.55
6	30	0	31	17824.94
6	31	0	31	17832.12
6	32	0	31	17840.63
7	30	0	31	17909.39
7	31	0	31	17916.41
7	32	0	31	17924.87
8	30	0	31	17992.15
8	31	0	31	17999.12
8	32	0	31	18007.37
9	31	0	31	18080.05
10	30	0	31	18152.78
10	31	0	31	18159.47
11	31	0	31	18237.99
12	31	0	31	18315.34
13	31	0	31	18392.14
3	32	0	32	17563.23
4	32	0	32	17653.73
5	32	0	32	17741.95
6	31	0	32	17820.77
6	32	0	32	17828.14
7	31	0	32	17905.09
7	32	0	32	17912.33
8	32	0	32	17994.92
9	32	0	32	18075.72
10	32	0	32	18155.06
11	32	0	32	18233.52
3	34	0	34	17555.86
4	34	0	34	17646.11
5	34	0	34	17734.05
6	34	0	34	17819.86
7	34	0	34	17903.78
8	34	0	34	17986.54
9	34	0	34	18066.66
0	34	0	35	17258.48
0	36	0	35	17278.21
1	34	0	35	17356.21
1	36	0	35	17375.39
2	34	0	35	17451.29
2	36	0	35	17470.15
3	34	0	35	17543.72
3	35	0	35	17551.91
3	36	0	35	17562.26
4	34	0	35	17633.92
4	35	0	35	17642.03
4	36	0	35	17652.13
5	34	0	35	17721.74
5	35	0	35	17729.83
5	36	0	35	17739.66
6	34	0	35	17807.59
6	35	0	35	17815.55
6	36	0	35	17825.20
7	34	0	35	17891.50
7	35	0	35	17899.36
7	36	0	35	17908.86
8	34	0	35	17973.82
8	35	0	35	17981.15
8	36	0	35	17990.90
9	35	0	35	18062.06
10	34	0	35	18133.55
10	35	0	35	18141.04
10	36	0	35	18150.16
11	35	0	35	18219.04
3	37	0	37	17543.89
3	38	0	37	17554.76
4	37	0	37	17633.62
5	37	0	37	17721.08
6	37	0	37	17806.50
7	37	0	37	17890.01
7	38	0	37	17900.05
8	37	0	37	17971.68
9	37	0	37	18052.17
10	37	0	37	18130.96
11	37	0	37	18208.80
12	37	0	37	18285.64
3	38	0	39	17526.29
3	39	0	39	17535.32
3	40	0	39	17546.80
4	38	0	39	17615.87
4	39	0	39	17624.76
5	38	0	39	17703.04
5	39	0	39	17711.89
5	40	0	39	17722.86
6	38	0	39	17788.25
6	39	0	39	17797.04
6	40	0	39	17807.73
7	38	0	39	17871.58
7	39	0	39	17880.21
7	40	0	39	17890.75
8	38	0	39	17953.40
8	39	0	39	17961.58
8	40	0	39	17972.34
9	38	0	39	18033.02
9	39	0	39	18041.84
9	40	0	39	18051.71
10	38	0	39	18112.10
10	39	0	39	18120.30
10	40	0	39	18130.81
11	38	0	39	18190.05
11	39	0	39	18197.94
12	39	0	39	18274.63
3	39	0	40	17521.65
3	40	0	40	17530.80
3	41	0	40	17542.68
4	39	0	40	17611.17
4	40	0	40	17620.11
4	41	0	40	17631.57
5	39	0	40	17698.07
5	40	0	40	17707.11
5	41	0	40	17718.35
6	39	0	40	17783.11
6	40	0	40	17792.03
6	41	0	40	17803.05
7	39	0	40	17866.14
7	40	0	40	17875.08
7	41	0	40	17885.97
8	39	0	40	17948.00
8	40	0	40	17956.38
9	40	0	40	18036.46
10	40	0	40	18114.75
11	40	0	40	18192.22
12	40	0	40	18268.89
4	41	0	42	17600.84
4	42	0	42	17610.51
4	43	0	42	17622.32
5	41	0	42	17687.63
5	42	0	42	17697.10
5	43	0	42	17708.87
6	41	0	42	17772.33
6	42	0	42	17781.79
6	43	0	42	17793.25
7	41	0	42	17855.21
7	42	0	42	17864.42
7	43	0	42	17875.77
8	41	0	42	17936.60
8	42	0	42	17945.44
10	42	0	42	18103.33
11	42	0	42	18180.52
12	42	0	42	18256.92
13	42	0	42	18332.31
1	42	0	43	17322.39
1	44	0	43	17345.68
2	42	0	43	17415.95
2	44	0	43	17438.90
3	42	0	43	17506.96
3	44	0	43	17529.41
1	44	0	45	17312.87
1	46	0	45	17337.16
2	46	0	45	17429.91
3	44	0	45	17496.58
3	46	0	45	17519.96
4	44	0	45	17584.96
4	45	0	45	17595.09
4	46	0	45	17608.00
5	44	0	45	17671.17
5	45	0	45	17681.23
5	46	0	45	17693.78
6	44	0	45	17755.31
6	45	0	45	17765.24
7	44	0	45	17837.75
7	45	0	45	17847.50
7	46	0	45	17859.70
8	44	0	45	17918.76
8	45	0	45	17928.07
8	46	0	45	17940.47
9	45	0	45	18006.90
10	44	0	45	18075.76
10	45	0	45	18085.08
10	46	0	45	18096.75
11	44	0	45	18152.95
11	45	0	45	18161.89
12	44	0	45	18229.49
12	45	0	45	18238.25
4	45	0	46	17579.43
4	46	0	46	17589.84
4	47	0	46	17602.89
5	45	0	46	17665.45
5	46	0	46	17675.67
5	47	0	46	17688.47
6	45	0	46	17749.44
6	46	0	46	17759.54
6	47	0	46	17772.18
7	45	0	46	17831.65
7	46	0	46	17841.65
7	47	0	46	17854.01
8	45	0	46	17912.62
8	46	0	46	17921.95
8	47	0	46	17934.77
9	46	0	46	18000.76
9	47	0	46	18012.60
10	45	0	46	18069.23
10	46	0	46	18078.67
10	47	0	46	18090.63
11	45	0	46	18146.37
11	46	0	46	18155.36
11	47	0	46	18167.44
0	46	0	47	17207.62
0	48	0	47	17233.35
1	46	0	47	17302.91
1	48	0	47	17328.18
2	46	0	47	17395.72
2	48	0	47	17420.53
3	46	0	47	17485.72
3	48	0	47	17510.05
4	48	0	47	17597.75
4	46	0	47	17573.77
4	47	0	47	17584.33
4	48	0	47	17597.76
5	46	0	47	17659.53
5	47	0	47	17669.98
5	48	0	47	17683.08
6	46	0	47	17743.40
6	47	0	47	17753.70
6	48	0	47	17766.48
7	46	0	47	17825.43
7	47	0	47	17835.61
7	48	0	47	17848.24
8	46	0	47	17906.20
8	47	0	47	17915.75
8	48	0	47	17928.83
9	47	0	47	17994.41
11	47	0	47	18148.70
4	48	0	49	17562.09
4	49	0	49	17573.02
4	50	0	49	17586.95
5	48	0	49	17647.50
5	49	0	49	17658.34
5	50	0	49	17671.87
6	48	0	49	17730.91
6	49	0	49	17741.58
7	49	0	49	17822.88
8	49	0	49	17902.87
9	49	0	49	17981.33
10	49	0	49	18058.66
1	49	0	50	17287.22
1	51	0	50	17313.92
2	49	0	50	17379.28
2	51	0	50	17405.58
3	49	0	50	17468.51
3	51	0	50	17494.11
4	49	0	50	17556.08
4	51	0	50	17581.40
5	49	0	50	17641.32
5	51	0	50	17666.18
6	49	0	50	17724.53
6	51	0	50	17749.02
7	49	0	50	17806.12
7	51	0	50	17830.21
3	52	0	52	17468.29
4	52	0	52	17555.16
4	53	0	52	17569.80
5	51	0	52	17628.33
5	52	0	52	17639.76
5	53	0	52	17654.10
6	51	0	52	17711.09
6	52	0	52	17722.38
6	53	0	52	17736.48
7	51	0	52	17792.30
7	52	0	52	17803.18
8	53	0	52	17896.83
9	52	0	52	17960.45
10	52	0	52	18037.32
11	52	0	52	18113.26
1	52	0	53	17270.54
1	54	0	53	17298.71
2	52	0	53	17361.89
2	54	0	53	17389.56
4	52	0	53	17537.17
4	54	0	53	17563.82
5	52	0	53	17621.72
5	54	0	53	17647.89
6	52	0	53	17704.31
6	54	0	53	17730.10
7	52	0	53	17785.30
7	54	0	53	17810.73
8	52	0	53	17864.85
5	54	0	54	17626.75
5	55	0	54	17641.63
6	53	0	54	17697.28
6	54	0	54	17708.93
6	55	0	54	17723.59
7	53	0	54	17778.16
7	54	0	54	17789.36
7	55	0	54	17804.05
8	54	0	54	17868.28
9	54	0	54	17945.93
10	54	0	54	18022.43
11	54	0	54	18098.12
12	54	0	54	18172.59
13	54	0	54	18246.64
14	54	0	54	18319.70
7	20	1	20	17770.50
7	21	1	20	17775.97
8	19	1	20	17849.54
8	20	1	20	17854.18
8	21	1	20	17859.59
9	19	1	20	17931.82
9	20	1	20	17936.18
9	21	1	20	17941.64
10	20	1	20	18016.61
10	21	1	20	18021.86
11	19	1	20	18091.62
11	20	1	20	18096.01
11	21	1	20	18101.23
12	19	1	20	18169.95
12	20	1	20	18174.28
5	27	1	27	17578.10
7	26	1	27	17743.45
7	27	1	27	17749.67
7	28	1	27	17757.05
8	26	1	27	17826.59
8	27	1	27	17832.71
8	28	1	27	17839.94
9	26	1	27	17908.37
9	27	1	27	17914.13
10	27	1	27	17993.96
11	27	1	27	18072.85
12	26	1	27	18145.14
12	27	1	27	18150.58
12	28	1	27	18157.74
13	27	1	27	18227.52
5	33	1	33	17556.80
7	33	1	33	17726.90
8	32	1	33	17801.99
8	33	1	33	17809.42
8	34	1	33	17818.13
9	33	1	33	17890.01
10	32	1	33	17962.18
10	33	1	33	17969.29
10	34	1	33	17977.91
11	32	1	33	18040.71
11	33	1	33	18047.54
12	32	1	33	18118.22
12	33	1	33	18124.77
12	34	1	33	18133.60
13	33	1	33	18201.82
14	33	1	33	18276.64
7	38	1	38	17704.42
8	37	1	38	17777.89
8	38	1	38	17785.97
8	39	1	38	17796.38
9	37	1	38	17857.64
9	38	1	38	17866.31
10	37	1	38	17936.89
10	38	1	38	17944.91
10	39	1	38	17954.81
11	37	1	38	18014.91
11	38	1	38	18022.59
12	37	1	38	18091.96
12	38	1	38	18099.39
12	39	1	38	18109.63
13	38	1	38	18175.01
14	38	1	38	18250.35
7	41	1	41	17689.30
8	40	1	41	17761.89
8	41	1	41	17770.48
9	41	1	41	17850.57
10	40	1	41	17920.10
10	41	1	41	17928.63
10	42	1	41	17939.34
11	40	1	41	17997.79
11	41	1	41	18006.01
12	40	1	41	18074.63
12	41	1	41	18082.48
12	42	1	41	18093.54
13	41	1	41	18157.86
14	41	1	41	18232.83
2	42	1	43	17235.66
2	44	1	43	17258.56
3	42	1	43	17326.64
3	44	1	43	17349.12
4	42	1	43	17415.39
4	44	1	43	17437.45
5	42	1	43	17501.91
5	44	1	43	17523.60
7	43	1	43	17678.61
8	42	1	43	17750.57
8	43	1	43	17759.48
8	44	1	43	17771.30
9	42	1	43	17829.54
10	42	1	43	17908.15
10	43	1	43	17917.05
10	44	1	43	17928.24
11	42	1	43	17985.60
11	43	1	43	17994.17
11	44	1	43	18005.53
12	42	1	43	18062.32
12	43	1	43	18070.48
14	43	1	43	18220.38
7	44	1	44	17673.08
8	44	1	44	17753.81
9	44	1	44	17832.75
10	43	1	44	17901.99
10	44	1	44	17911.08
10	45	1	44	17922.55
11	43	1	44	17979.44
11	44	1	44	17988.10
12	43	1	44	18055.97
12	44	1	44	18064.41
14	44	1	44	18214.02
2	44	1	45	17226.00
2	46	1	45	17249.87
3	44	1	45	17316.54
3	46	1	45	17339.93
4	44	1	45	17404.93
4	46	1	45	17427.95
5	44	1	45	17491.09
5	46	1	45	17513.70
8	49	1	49	17723.33
9	49	1	49	17801.71
10	48	1	49	17869.12
10	49	1	49	17879.05
11	49	1	49	17955.42
12	49	1	49	18030.62
13	49	1	49	18105.30
2	53	1	52	17215.82
3	51	1	52	17277.13
3	53	1	52	17304.29
4	51	1	52	17364.40
4	53	1	52	17390.61
5	51	1	52	17449.12
5	53	1	52	17474.87
2	55	1	54	17205.08
4	53	1	54	17351.76
4	55	1	54	17378.85
5	55	1	54	17462.72
3	58	1	59	17233.60
3	60	1	59	17263.38
4	58	1	59	17317.92
4	60	1	59	17347.14
5	58	1	59	17401.07
5	60	1	59	17429.83
0	18	2	19	16942.22
0	20	2	19	16953.15
1	18	2	19	17041.87
1	20	2	19	17052.56
2	18	2	19	17138.83
2	20	2	19	17149.38
3	18	2	19	17233.29
3	20	2	19	17243.69
4	18	2	19	17325.39
5	18	2	19	17415.11
5	20	2	19	17425.08
6	18	2	19	17502.72
6	20	2	19	17512.58
0	20	2	20	16945.29
1	19	2	20	17039.65
1	20	2	20	17044.77
1	21	2	20	17050.92
2	19	2	20	17136.63
2	20	2	20	17141.61
0	24	2	24	16937.12
1	24	2	24	17036.06
2	24	2	24	17132.62
0	25	2	26	16925.95
0	27	2	26	16940.62
1	25	2	26	17024.80
1	27	2	26	17039.30
2	25	2	26	17121.08
2	27	2	26	17135.30
3	25	2	26	17214.84
3	27	2	26	17228.86
4	25	2	26	17306.25
4	27	2	26	17319.96
5	25	2	26	17395.28
5	27	2	26	17408.79
6	25	2	26	17482.22
6	27	2	26	17495.52
7	25	2	26	17567.25
7	27	2	26	17580.27
7	26	2	26	17573.29
12	26	2	26	17974.65
0	31	2	32	16908.44
0	32	2	32	16916.06
0	33	2	32	16926.40
1	31	2	32	17006.52
1	32	2	32	17014.12
1	33	2	32	17024.19
2	32	2	32	17109.58
2	33	2	32	17119.40
3	31	2	32	17194.94
3	32	2	32	17202.57
4	31	2	32	17285.56
4	32	2	32	17293.11
0	35	2	36	16894.80
0	36	2	36	16903.35
0	37	2	36	16914.56
1	35	2	36	16992.40
1	36	2	36	17000.76
1	37	2	36	17012.13
2	35	2	36	17087.27
2	36	2	36	17095.65
2	37	2	36	17106.64
3	36	2	36	17187.98
7	36	2	36	17534.87
0	41	2	42	16871.88
0	42	2	42	16881.39
0	43	2	42	16895.03
1	41	2	42	16968.20
1	42	2	42	16977.73
1	43	2	42	16991.02
2	41	2	42	17062.02
2	42	2	42	17071.57
2	43	2	42	17084.43
3	42	2	42	17162.83
0	46	2	47	16850.05
0	47	2	47	16860.41
0	48	2	47	16875.74
1	46	2	47	16945.37
1	47	2	47	16955.79
1	48	2	47	16970.68
2	46	2	47	17038.16
2	47	2	47	17048.55
2	48	2	47	17062.96
3	46	2	47	17128.29
0	49	2	49	16851.36
1	48	2	49	16935.49
1	49	2	49	16946.25
1	50	2	49	16961.75
2	48	2	49	17027.79
2	49	2	49	17038.59
2	50	2	49	17053.57
3	48	2	49	17117.29
3	49	2	49	17128.43
1	51	2	52	16919.88
1	53	2	52	16947.65
2	51	2	52	17011.52
2	53	2	52	17038.71
3	51	2	52	17100.05
3	53	2	52	17127.19
5	51	2	52	17272.02
5	53	2	52	17297.80
6	51	2	52	17354.85
6	53	2	52	17380.25
7	51	2	52	17436.04
7	53	2	52	17461.02
8	51	2	52	17515.49
8	53	2	52	17540.50
0	51	2	52	16825.75
0	53	2	52	16853.96
1	51	2	52	16919.93
1	52	2	52	16931.22
1	53	2	52	16947.61
2	51	2	52	17011.56
2	52	2	52	17022.87
2	53	2	52	17038.72
3	52	2	52	17112.02
5	51	2	52	17272.04
5	52	2	52	17283.44
1	54	2	55	16903.40
1	56	2	55	16932.50
2	54	2	55	16994.25
2	56	2	55	17022.85
5	54	2	55	17252.63
5	56	2	55	17279.71
6	54	2	55	17334.85
6	56	2	55	17361.47
7	54	2	55	17415.45
7	56	2	55	17441.73
8	54	2	55	17494.82
8	56	2	55	17520.89
0	54	2	55	16810.08
0	56	2	55	16839.71
1	54	2	55	16903.42
1	55	2	55	16915.26
1	56	2	55	16932.55
2	54	2	55	16994.31
2	55	2	55	17006.16
2	56	2	55	17022.84
4	41	3	42	17065.80
4	43	3	42	17087.43
5	41	3	42	17152.64
5	43	3	42	17173.84
6	41	3	42	17237.32
6	43	3	42	17258.23
0	45	3	45	16693.15
1	45	3	45	16788.92
4	53	3	54	17000.15
4	55	3	54	17027.24
5	53	3	54	17084.45
5	55	3	54	17111.10
6	53	3	54	17166.87
6	55	3	54	17193.06
5	58	3	59	17050.94
5	60	3	59	17079.79
6	58	3	59	17132.34
6	60	3	59	17160.66

b) IPA potential for the (5)1 state

       R[A]    V[cm-1]        R[A]    V[cm-1]
       2.0   41657.5254       6.0   18525.0124
       2.2   33438.2736       6.2   18692.6947
       2.4   28511.8055       6.4   18890.3182
       2.6   25068.4866       6.6   19080.8375
       2.8   22602.3928       6.8   19262.9631
       3.0   20857.9907       7.0   19431.8117
       3.2   19565.0494       7.4   19702.2591
       3.4   18657.0681       7.8   19873.1624
       3.6   18038.6637       8.2   19994.6218
       3.8   17646.3251       8.6   20088.7638
       4.0   17439.9321       9.0   20162.2408
       4.2   17370.3380       9.4   20219.0773
       4.4   17392.7327       9.8   20262.5152
       4.6   17474.9263      10.2   20295.3384
       4.8   17593.2340      11.0   20338.2737
       5.0   17731.4981      12.0   20361.6037
       5.2   17880.7029      14.0   20370.4423
       5.4   18035.4118      16.0   20373.0849
       5.6   18194.5569      18.0   20374.0333
       5.8   18354.6506      20.0   20374.4199
     q   = 0.1064(32)E-02   
     q_v = -0.226(15)E-04   
     q_J = -0.626(64)E-05   

3. The (5)0^+ state

a) Observed spectral lines in the (5)0^+ <-- X band system

v'     J'   v"    J"  wave number [cm-1]
3	18	0	19	17444.55
3	20	0	19	17454.81
4	18	0	19	17540.35
4	20	0	19	17550.39
5	18	0	19	17635.45
5	20	0	19	17645.27
6	18	0	19	17731.70
6	20	0	19	17741.39
7	18	0	19	17830.39
7	20	0	19	17839.99
8	18	0	19	17929.83
8	20	0	19	17939.39
9	18	0	19	18028.83
9	20	0	19	18037.69
6	22	0	23	17719.97
6	24	0	23	17731.57
7	22	0	23	17818.47
8	22	0	23	17917.74
8	24	0	23	17929.18
4	24	0	25	17523.30
5	24	0	25	17617.66
5	26	0	25	17630.53
6	24	0	25	17713.39
6	26	0	25	17725.99
7	24	0	25	17811.81
7	26	0	25	17824.34
8	24	0	25	17911.07
8	26	0	25	17923.49
9	24	0	25	18009.21
10	24	0	25	18105.38
10	26	0	25	18117.56
3	27	0	28	17418.23
4	27	0	28	17513.00
4	29	0	28	17527.59
5	27	0	28	17607.07
5	29	0	28	17621.39
6	27	0	28	17702.42
6	29	0	28	17716.53
7	27	0	28	17800.69
7	29	0	28	17814.64
8	27	0	28	17899.79
8	29	0	28	17913.70
9	27	0	28	17997.81
9	29	0	28	18011.57
5	28	0	29	17603.23
5	30	0	29	17618.05
6	28	0	29	17698.60
6	30	0	29	17713.10
7	28	0	29	17796.71
7	30	0	29	17811.31
8	28	0	29	17895.86
8	30	0	29	17910.18
9	28	0	29	17993.75
9	30	0	29	18008.97
10	28	0	29	18089.63
10	30	0	29	18103.64
11	28	0	29	18181.66
3	29	0	30	17411.14
3	31	0	30	17427.02
4	29	0	30	17505.72
4	31	0	30	17521.28
5	29	0	30	17599.42
5	31	0	30	17614.77
6	29	0	30	17694.59
6	31	0	30	17709.63
7	29	0	30	17792.76
7	31	0	30	17807.67
8	29	0	30	17891.75
8	31	0	30	17906.59
9	29	0	30	17989.64
9	31	0	30	18004.35
5	30	0	31	17595.38
5	32	0	31	17611.13
6	30	0	31	17690.43
6	32	0	31	17705.98
7	30	0	31	17788.46
7	32	0	31	17803.67
8	30	0	31	17887.53
8	32	0	31	17902.79
9	30	0	31	17985.32
9	32	0	31	18000.38
6	31	0	32	17686.11
6	33	0	32	17702.17
7	33	0	32	17800.06
8	31	0	32	17883.13
3	34	0	35	17391.49
3	36	0	35	17409.90
4	34	0	35	17485.26
4	36	0	35	17503.33
5	34	0	35	17578.22
5	36	0	35	17595.94
6	34	0	35	17672.67
6	36	0	35	17690.12
7	34	0	35	17770.46
7	36	0	35	17787.74
8	34	0	35	17869.25
8	36	0	35	17886.44
9	34	0	35	17966.78
9	36	0	35	17983.76
10	34	0	35	18062.11
10	36	0	35	18078.86
11	34	0	35	18152.85
11	36	0	35	18169.14
5	36	0	37	17568.89
5	38	0	37	17587.61
7	36	0	37	17760.63
7	38	0	37	17778.95
5	38	0	39	17559.09
5	40	0	39	17578.76
6	38	0	39	17653.00
6	40	0	39	17672.28
7	38	0	39	17750.44
7	40	0	39	17769.51
8	38	0	39	17848.97
8	40	0	39	17867.95
9	38	0	39	17946.10
9	40	0	39	17964.93
5	39	0	40	17554.04
5	41	0	40	17574.04
6	39	0	40	17647.75
6	41	0	40	17667.53
7	39	0	40	17745.15
7	41	0	40	17764.78
8	39	0	40	17843.62
8	41	0	40	17863.09
9	39	0	40	17940.65
9	41	0	40	17959.88
10	39	0	40	18035.33
10	41	0	40	18054.37
11	39	0	40	18124.93
11	41	0	40	18143.32
6	41	0	42	17636.83
6	43	0	42	17657.60
7	41	0	42	17734.13
7	43	0	42	17754.63
8	41	0	42	17832.32
9	43	0	42	17949.28
4	42	0	43	17446.53
4	44	0	43	17468.44
5	42	0	43	17537.99
5	44	0	43	17559.50
3	46	0	45	17367.01
4	44	0	45	17435.63
4	46	0	45	17458.53
5	44	0	45	17526.73
5	46	0	45	17549220
6	44	0	45	17619.59
6	46	0	45	17641.71
7	44	0	45	17716.55
7	46	0	45	17738.48
8	44	0	45	17814.62
8	46	0	45	17836.36
9	44	0	45	17911.05
9	46	0	45	17932.42
10	44	0	45	18005.03
10	46	0	45	18026.17
5	45	0	46	17520.85
5	47	0	46	17543.86
6	45	0	46	17613.64
6	47	0	46	17636.16
7	45	0	46	17710.50
7	47	0	46	17732.88
8	45	0	46	17808.42
8	47	0	46	17830.62
9	47	0	46	17926.52
10	45	0	46	17998.57
10	47	0	46	18020.17
11	45	0	46	18086.20
11	47	0	46	18107.08
3	46	0	47	17332.79
3	48	0	47	17357.04
4	46	0	47	17424.33
4	48	0	47	17448.17
5	46	0	47	17515.00
5	48	0	47	17538.39
6	46	0	47	17607.49
6	48	0	47	17630.51
7	46	0	47	17704.24
7	48	0	47	17727.10
8	46	0	47	17802.16
8	48	0	47	17824.76
9	48	0	47	17920.53
5	50	0	49	17527.05
6	48	0	49	17595.68
6	50	0	49	17618.82
7	48	0	49	17691.47
7	50	0	49	17715.18
8	48	0	49	17789.16
8	50	0	49	17812.69
3	49	0	50	17315.56
3	51	0	50	17341.25
4	49	0	50	17406.44
4	51	0	50	17431.66
5	51	0	50	17521.26
6	49	0	50	17588.60
6	51	0	50	17612.89
7	49	0	50	17685.00
7	51	0	50	17709.18
8	49	0	50	17782.56
8	51	0	50	17806.53
9	49	0	50	17878.11
9	51	0	50	17901.67
10	49	0	50	17971.30
10	51	0	50	17994.54
5	51	0	52	17483.45
5	53	0	52	17509.10
6	51	0	52	17575.02
6	53	0	52	17600.29
7	51	0	52	17671.31
7	53	0	52	17696.36
8	53	0	52	17793.47
9	51	0	52	17863.78
9	53	0	52	17888.11
3	52	0	53	17297.30
3	54	0	53	17324.37
4	52	0	53	17387.46
4	54	0	53	17414.09
5	52	0	53	17476.57
5	54	0	53	17502.97
6	52	0	53	17568.15
6	54	0	53	17593.92
7	52	0	53	17664.31
7	54	0	53	17689.82
8	52	0	53	17761.53
8	54	0	53	17786.79
9	52	0	53	17856.48
9	54	0	53	17881.29
10	52	0	53	17949.17
10	54	0	53	17973.62
7	53	0	54	17657.24
7	55	0	54	17683.18
8	53	0	54	17754.33
8	55	0	54	17780.03
7	19	1	20	17645.41
7	21	1	20	17655.49
8	19	1	20	17744.79
8	21	1	20	17754.82
9	19	1	20	17843.13
9	21	1	20	17853.11
10	21	1	20	17949.42
11	19	1	20	18032.87
11	21	1	20	18042.50
7	26	1	27	17622.78
8	26	1	27	17721.94
8	28	1	27	17735.28
9	26	1	27	17819.96
9	28	1	27	17833.21
10	26	1	27	17915.94
10	28	1	27	17929.13
11	26	1	27	18008.33
11	28	1	27	18021.16
8	34	1	33	17713.63
9	32	1	33	17795.03
10	32	1	33	17890.60
10	34	1	33	17906.42
11	34	1	33	17997.29
7	37	1	38	17574.86
7	39	1	38	17593.54
8	37	1	38	17673.46
8	39	1	38	17691.98
9	37	1	38	17770.67
9	39	1	38	17789.02
10	37	1	38	17865.66
10	39	1	38	17883.64
11	37	1	38	17955.75
11	39	1	38	17973.32
7	40	1	41	17559.14
8	40	1	41	17657.56
8	42	1	41	17677.47
9	40	1	41	17754.49
9	42	1	41	17774.17
10	40	1	41	17848.55
10	42	1	41	17868.48
11	40	1	41	17938.28
11	42	1	41	17957.16
4	42	1	43	17266.18
4	44	1	43	17288.14
5	42	1	43	17357.68
5	44	1	43	17379.21
7	42	1	43	17548.05
7	44	1	43	17569.07
8	42	1	43	17646.30
9	42	1	43	17742.99
10	42	1	43	17837.25
10	44	1	43	17857.56
11	42	1	43	17925.94
11	44	1	43	17945.58
7	45	1	44	17563.82
8	43	1	44	17640.53
8	45	1	44	17661.78
9	43	1	44	17737.10
10	43	1	44	17831.26
10	45	1	44	17851.92
11	43	1	44	17919.60
11	45	1	44	17939.57
4	44	1	45	17255.59
4	46	1	45	17278.48
5	44	1	45	17346.65
5	46	1	45	17369.18
7	44	1	45	17536.48
7	46	1	45	17558.44
4	51	1	52	17214.71
4	53	1	52	17240.87
5	51	1	52	17303.39
5	53	1	52	17329.96
7	51	1	52	17492.08
7	53	1	52	17517.17
4	53	1	54	17202.01
4	55	1	54	17229.08
7	53	1	54	17478.29
7	58	1	59	17441.66
7	60	1	59	17469.79
8	58	1	59	17538.03
8	60	1	59	17565.84
5	18	2	19	17272.98
5	20	2	19	17282.85
6	18	2	19	17369.22
6	20	2	19	17378.95
7	18	2	19	17467.95
7	20	2	19	17477.53
5	25	2	26	17252.61
5	27	2	26	17265.94
6	25	2	26	17348.16
6	27	2	26	17361.27
7	25	2	26	17446.57
7	27	2	26	17459.55
3	31	2	32	17042.95
4	31	2	32	17137.25
5	31	2	32	17230.59
3	35	2	36	17027.24
6	35	2	36	17307.96
6	37	2	36	17325.87
3	43	2	42	17022.32
3	48	2	47	16999.48
6	51	2	52	17218.75
6	53	2	52	17244.05
7	51	2	52	17314.99
7	53	2	52	17340.10
8	51	2	52	17412.35
8	53	2	52	17437.15
6	54	2	55	17198.64
6	56	2	55	17225.27
7	54	2	55	17294.53
7	56	2	55	17320.97
8	54	2	55	17391.48
8	56	2	55	17417.64
7	41	3	42	17199.03
7	43	3	42	17219.57
8	41	3	42	17297.32
8	43	3	42	17317.70
9	41	3	42	17394.12
9	43	3	42	17414.25
7	53	3	54	17126.76
7	55	3	54	17152.70
8	53	3	54	17223.83
8	55	3	54	17249.53
9	53	3	54	17318.52
9	55	3	54	17343.75
10	53	3	54	17411.06
10	55	3	54	17435.88
6	60	3	59	17024.04
7	58	3	59	17091.55
7	60	3	59	17119.69
8	58	3	59	17187.95
8	60	3	59	17215.73
10	58	3	59	17372.95
10	60	3	59	17399.85

b) IPA potential for the (5)0^+ state

       R[A]    V[cm-1]        R[A]    V[cm-1]
       2.0   41797.5253       5.8   18379.9443
       2.4   28651.8160       6.0   18604.1803
       2.6   25208.4417       6.4   18974.8626
       2.8   22742.5630       6.8   19296.7507
       3.0   20997.3546       7.2   19571.4772
       3.2   19757.4244       7.6   19827.7357
       3.4   18889.7423       8.0   20003.5462
       3.6   18165.6026       8.4   20135.8234
       3.7   17873.4376       8.8   20220.7238
       3.8   17592.4829       9.2   20276.6893
       4.0   17392.2483       9.6   20317.6864
       4.2   17213.2193      10.0   20347.0153
       4.5   17223.0686      12.0   20432.8549
       4.8   17374.9584      14.0   20464.1486
       5.0   17559.4056      16.0   20470.2963
       5.2   17719.6727      18.0   20471.4621
       5.4   17919.7225      20.0   20471.9322
       5.6   18173.3986

4. The (6)1 state

a) Observed spectral lines in the (6)1 <-- X band system

v'     J'   v"    J"  wave number [cm-1]
1	18	0	19	17785.73
1	20	0	19	17796.63
2	18	0	19	17895.93
2	20	0	19	17906.69
3	18	0	19	18003.36
3	20	0	19	18013.94
4	18	0	19	18107.82
4	20	0	19	18118.21
3	23	0	23	17993.78
4	23	0	23	18098.08
5	23	0	23	18199.69
2	25	0	25	17881.26
3	25	0	25	17988.20
4	25	0	25	18092.26
5	25	0	25	18193.68
1	27	0	28	17763.11
1	28	0	28	17762.66
1	29	0	28	17778.98
2	27	0	28	17872.41
2	28	0	28	17872.43
2	29	0	28	17888.03
3	27	0	28	17978.98
3	28	0	28	17978.84
3	29	0	28	17994.04
4	27	0	28	18082.30
4	28	0	28	18082.48
4	29	0	28	18097.21
5	27	0	28	18183.52
5	28	0	28	18183.52
5	29	0	28	18198.47
6	28	0	28	18281.52
6	29	0	28	18296.10
1	28	0	29	17760.06
1	29	0	29	17759.59
1	30	0	29	17776.46
2	28	0	29	17869.22
2	29	0	29	17868.90
2	30	0	29	17885.43
3	29	0	29	17975.41
3	30	0	29	17991.63
4	28	0	29	18079.08
4	29	0	29	18079.08
5	28	0	29	18179.97
5	29	0	29	18179.97
5	30	0	29	18195.54
6	28	0	29	18277.02
6	30	0	29	18292.99
1	29	0	30	17757.02
1	31	0	30	17774.01
2	29	0	30	17866.16
2	31	0	30	17882.88
3	29	0	30	17972.47
3	31	0	30	17988.89
5	29	0	30	18176.62
5	31	0	30	18192.53
2	30	0	31	17862.83
2	31	0	31	17862.21
2	32	0	31	17880.10
3	30	0	31	17968.90
3	31	0	31	17968.46
3	32	0	31	17985.91
5	30	0	31	18172.86
5	31	0	31	18172.44
5	32	0	31	18189.30
6	30	0	31	18270.24
6	31	0	31	18270.03
3	32	0	32	17964.88
4	32	0	32	18068.06
6	32	0	32	18266.07
1	34	0	35	17740.11
1	35	0	35	17739.03
1	36	0	35	17759.83
2	34	0	35	17848.62
2	35	0	35	17847.57
2	36	0	35	17868.02
3	34	0	35	17954.22
3	35	0	35	17953.30
3	36	0	35	17973.30
4	35	0	35	18056.11
5	34	0	35	18156.96
5	35	0	35	18156.30
5	36	0	35	18175.38
6	35	0	35	18253.24
2	37	0	37	17839.64
3	37	0	37	17945.07
5	36	0	37	18148.33
5	37	0	37	18147.30
6	37	0	37	18244.09
6	38	0	37	18263.94
8	37	0	37	18428.47
1	38	0	39	17725.03
1	39	0	39	17723.43
2	38	0	39	17832.89
2	39	0	39	17831.36
2	40	0	39	17854.34
3	38	0	39	17937.85
3	39	0	39	17936.45
3	40	0	39	17959.01
4	38	0	39	18040.18
4	39	0	39	18038.56
4	40	0	39	18060.91
5	38	0	39	18139.23
5	39	0	39	18138.17
5	40	0	39	18159.69
6	38	0	39	18235.47
6	39	0	39	18234.50
6	40	0	39	18255.53
8	38	0	39	18419.33
8	39	0	39	18418.17
1	39	0	40	17721.10
1	41	0	40	17743.44
2	39	0	40	17828.78
2	40	0	40	17827.15
2	41	0	40	17850.78
3	39	0	40	17933.58
3	40	0	40	17931.87
3	41	0	40	17955.21
4	39	0	40	18035.82
4	41	0	40	18056.97
5	39	0	40	18134.58
5	40	0	40	18133.33
5	41	0	40	18155.50
6	40	0	40	18229.51
7	39	0	40	18323.58
7	40	0	40	18322.50
7	41	0	40	18343.93
8	40	0	40	18412.68
1	42	0	42	17710.64
2	42	0	42	17818.12
3	41	0	42	17924.37
3	42	0	42	17922.85
4	41	0	42	18026.20
5	41	0	42	18124.75
5	42	0	42	18123.38
5	43	0	42	18146.70
6	41	0	42	18220.39
6	42	0	42	18219.13
7	41	0	42	18313.24
7	42	0	42	18311.83
8	42	0	42	18401.68
1	44	0	45	17699.44
1	45	0	45	17697.10
1	46	0	45	17724.40
2	44	0	45	17806.23
2	45	0	45	17804.02
2	46	0	45	17830.80
3	45	0	45	17908.20
4	44	0	45	18011.05
4	45	0	45	18009.53
4	46	0	45	18035.10
5	44	0	45	18109.32
5	45	0	45	18107.62
5	46	0	45	18132.64
6	45	0	45	18202.80
6	46	0	45	18227.44
7	44	0	45	18296.47
7	45	0	45	18295.08
8	44	0	45	18385.70
8	45	0	45	18383.99
9	44	0	45	18471.92
9	45	0	45	18470.64
4	45	0	46	18006.24
4	46	0	46	18004.21
4	47	0	46	18030.38
5	45	0	46	18103.92
5	46	0	46	18102.11
5	47	0	46	18127.75
6	45	0	46	18199.19
6	46	0	46	18197.15
6	47	0	46	18222.26
7	45	0	46	18290.72
7	46	0	46	18289.12
8	46	0	46	18377.76
8	47	0	46	18401.98
9	46	0	46	18464.28
1	47	0	47	17687.57
2	47	0	47	17794.22
4	46	0	47	18000.93
4	47	0	47	17998.76
4	48	0	47	18025.67
5	46	0	47	18098.43
5	47	0	47	18096.44
5	48	0	47	18122.70
6	46	0	47	18193.23
6	47	0	47	18191.34
7	47	0	47	18283.14
1	49	0	49	17677.70
2	49	0	49	17783.86
3	49	0	49	17887.24
4	48	0	49	17989.98
4	49	0	49	17987.61
4	50	0	49	18015.64
5	49	0	49	18084.92
7	49	0	49	18270.73
2	49	0	50	17781.50
2	51	0	50	17808.58
3	49	0	50	17884.07
3	51	0	50	17910.53
4	49	0	50	17984.41
4	51	0	50	18010.55
5	49	0	50	18081.30
5	51	0	50	18107.11
6	49	0	50	18175.33
6	51	0	50	18200.56
3	52	0	52	17870.27
4	52	0	52	17970.01
4	53	0	52	17999.75
5	51	0	52	18069.18
5	52	0	52	18066.67
6	51	0	52	18162.75
6	52	0	52	18160.33
7	51	0	52	18252.97
7	52	0	52	18251.04
8	52	0	52	18338.98
8	53	0	52	18365.98
2	52	0	53	17765.14
2	54	0	53	17793.73
3	52	0	53	17867.70
3	54	0	53	17895.64
4	52	0	53	17966.75
4	54	0	53	17994.35
5	52	0	53	18063.00
5	54	0	53	18090.10
3	54	0	54	17858.53
4	53	0	54	17960.64
4	54	0	54	17957.80
4	55	0	54	17988.72
5	53	0	54	18056.66
5	54	0	54	18054.01
5	55	0	54	18084.26
6	54	0	54	18147.07
7	54	0	54	18237.34
8	54	0	54	18324.71
1	20	1	20	17601.71
3	19	1	20	17818.87
3	20	1	20	17819.38
4	19	1	20	17923.25
4	20	1	20	17923.93
4	21	1	20	17934.43
5	20	1	20	18025.38
1	26	1	27	17584.18
1	27	1	27	17584.00
2	27	1	27	17693.61
3	27	1	27	17800.27
3	28	1	27	17815.20
4	26	1	27	17903.86
4	27	1	27	17904.06
4	28	1	27	17918.32
1	32	1	33	17565.98
1	33	1	33	17564.99
2	32	1	33	17674.63
2	33	1	33	17673.83
3	32	1	33	17780.66
3	33	1	33	17779.86
3	34	1	33	17798.52
9	33	1	33	18354.08
2	37	1	38	17656.19
2	38	1	38	17654.80
2	39	1	38	17677.18
3	37	1	38	17761.28
3	38	1	38	17760.01
3	39	1	38	17781.87
4	38	1	38	17862.32
8	38	1	38	18242.53
2	40	1	41	17643.86
2	41	1	41	17642.16
2	42	1	41	17666.47
3	40	1	41	17748.55
3	41	1	41	17747.07
4	41	1	41	17849.04
0	42	1	43	17418.08
0	44	1	43	17442.35
1	42	1	43	17528.04
1	43	1	43	17525.95
1	44	1	43	17551.97
2	42	1	43	17635.25
2	43	1	43	17633.30
2	44	1	43	17658.78
3	42	1	43	17739.43
3	43	1	43	17737.79
4	42	1	43	17841.01
7	42	1	43	18127.55
7	43	1	43	18126.09
9	42	1	43	18303.71
9	43	1	43	18302.66
2	43	1	44	17630.85
2	44	1	44	17628.76
2	45	1	44	17654.87
3	43	1	44	17734.82
3	44	1	44	17733.01
9	44	1	44	18296.69
0	44	1	45	17409.76
0	46	1	45	17435.11
1	44	1	45	17519.42
1	46	1	45	17544.31
2	48	1	49	17606.96
2	49	1	49	17604.33
3	49	1	49	17707.58
9	49	1	49	18265.33
10	49	1	49	18347.13
11	49	1	49	18426.58
0	51	1	52	17377.88
0	53	1	52	17406.81
1	51	1	52	17486.12
1	53	1	52	17514.62
0	53	1	54	17367.99
0	55	1	54	17397.98
1	55	1	54	17505.32
0	58	1	59	17341.61
0	60	1	59	17374.14
1	58	1	59	17448.25
1	60	1	59	17480.26
2	58	1	59	17551.98
2	60	1	59	17583.37
0	18	2	19	17310.22
0	20	2	19	17321.28
1	18	2	19	17423.27
1	20	2	19	17434.20
2	18	2	19	17533.49
0	19	2	20	17308.30
0	20	2	20	17308.70
0	21	2	20	17318.89
0	25	2	26	17294.66
0	27	2	26	17309.70
1	25	2	26	17407.12
1	27	2	26	17421.90
2	27	2	26	17531.28
0	31	2	32	17278.12
0	32	2	32	17277.25
0	33	2	32	17296.45
0	35	2	36	17265.37
0	36	2	36	17263.95
0	37	2	36	17285.91
0	41	2	42	17243.79
0	42	2	42	17241.58
0	43	2	42	17267.51
0	47	2	47	17220.53
0	48	2	47	17249.91
0	48	2	49	17214.57
0	49	2	49	17211.55
0	50	2	49	17242.13
1	48	2	49	17323.44
1	49	2	49	17320.61
0	51	2	52	17200.80
0	52	2	52	17197.34
0	53	2	52	17229.74
1	51	2	52	17309.02
1	52	2	52	17305.84
1	53	2	52	17337.57
2	51	2	52	17414.41
2	53	2	52	17442.47
0	54	2	55	17186.20
0	55	2	55	17182.45
0	56	2	55	17216.69
1	54	2	55	17293.78
1	55	2	55	17290.21
1	56	2	55	17323.83
2	54	2	55	17398.46
2	56	2	55	17427.96
0	41	3	42	17067.48
0	43	3	42	17091.19
1	41	3	42	17177.61
1	43	3	42	17201.04
0	53	3	54	17016.42
0	55	3	54	17046.33
1	53	3	54	17124.23
1	55	3	54	17153.75
4	53	3	54	17430.16
4	55	3	54	17458.24
1	58	3	59	17098.13
1	60	3	59	17130.18
3	58	3	59	17302.70
4	58	3	59	17400.43
4	60	3	59	17430.74

b) IPA potential for the (6)1 state

       R[A]    V[cm-1]      R[A]    V[cm-1]
       2.0   42917.2293     6.0   19065.6368
       2.2   33602.9415     6.2   19179.6347
       2.4   28908.3909     6.4   19300.1787
       2.6   25200.0161     6.6   19409.7377
       2.8   22698.1384     6.8   19512.5730
       3.0   21086.6426     7.0   19608.9677
       3.2   19993.5678     7.2   19701.8477
       3.4   19146.0702     7.4   19795.0028
       3.6   18432.2987     7.6   19888.8139
       3.8   17998.6276     8.0   20052.2440
       4.0   17786.3100     8.4   20169.2205
       4.2   17729.1571     8.8   20248.4750
       4.4   17778.9919     9.2   20300.9801
       4.6   17897.1936     9.6   20332.4014
       4.8   18055.4865    10.0   20347.5974
       5.0   18233.7236    12.0   20370.8770
       5.2   18416.7089    14.0   20373.3300
       5.4   18593.5162    16.0   20374.1662
       5.6   18762.7192    18.0   20374.4929
       5.8   18913.8816    20.0   20374.6362
q    = 0.14886(14)E-01
q_v  = -0.106(7)E-03
q_v2 = -0.64(9)E-05
q_J  = -0.2128(62)E-03
q_J2 = 0.95(7)E-06

5. The wave numbers corresponding to the labeling transitions 
in the D^1Pi <-- X^1Sigma^+ system of LiCs used in this experiment 
and energies of the labeled ground state levels calculated from 
the X state potential curve given by P. Staanum, A. Pashov, 
H. Knoeckel, and E. Tiemann, Phys. Rev. A 75, 042513 (2007).

wave number   labeled level in X        level energy (a) 
[cm-1]		(v,J)				[cm-1]
18492.2		(0,19)			163.14
			(0,28)			243.68
18492.9		(0,23)			195.24
18489.2		(0,25)			213.51
18483.15		(0,28)			243.68
18481.0		(0,29)			254.48
18488.7		(0,30)			265.64
18478.9		(0,30)			265.64
18476.4		(0,31)			277.16
18473.9		(0,32)			289.05
18470.4		(0,34)			313.93
18467.5		(0,35)			326.91
18457.0		(0,35)			326.91
			(0,43)			443.79
18461.9		(0,37)			353.96
18456.25		(0,39)			382.47
18465.7		(0,40)			397.26
18453.3		(0,40)			397.26
18447.2		(0,42)			427.92
18437.5		(0,45)			476.60
18424.6		(0,45)			476.60
			(0,53)			621.99
18434.2		(0,46)			493.53
18445.1		(0,47)			510.83
18430.7		(0,47)			510.83
18423.6		(0,49)			546.47
18405.7		(0,50)			564.83
18412.3		(0,52)			602.58
18404.3		(0,54)			641.74
18067.6		(1,20)			352.77
18190.9		(1,26)			405.00
18180.8		(1,27)			414.99
18168.3		(1,33)			482.57
18156.4		(1,38)			548.84
18148.1		(1,41)			592.91
18158.5		(1,42)			608.31
18142.3		(1,43)			624.07
18139.3		(1,44)			640.18
18123.1		(1,49)			726.03
18006.45		(1,52)			781.74
			(1,43)			624.07
18093.75		(1,53)			801.01
18000.0		(1,54)			820.62
			(1,45)			656.64
18077.4		(1,57)			881.52
17947.3		(1,59)			923.83
17883.0		(2,19)			525.54
17887.5		(2,20)			532.91
17881.84		(2,24)			566.04
18241.1		(2,25)			575.23
18246.7		(2,26)			584.78
17870.8		(2,26)			584.78
17867.4		(2,32)			649.72
18244.2		(2,32)			649.72
18224.6		(2,36)			700.22
17858.7		(2,36)			700.22
18211.3		(2,37)			713.74
17843.7		(2,42)			786.66
17829.3		(2,47)			868.40
17823.3		(2,49)			903.54
17829.3		(2,52)			958.86
17813.4		(2,52)			958.86
17803.05		(2,55)			1017.26
17819.9		(2,55)			1017.26
17704.9		(3,19)			703.70
			(3,29)			793.15
17711.65		(3,24)			743.91
17677.3		(3,38)			904.34
17667.4		(3,42)			962.96
17903.4		(3,45)			1010.61
17650.7		(3,48)			1061.38
17616.05		(3,54)			1172.21
17597.25		(3,59)			1273.91

(a) above the minimum of the ground state potential