Dimer

Study of excited electronic states of the ³⁹KCs molecule correlated with the K(4²S)+Cs(5²D) asymptote: experiment and theory

J. Szczepkowski, A. Grochola,W. Jastrzebski, P. Kowalczyk,  Romain Vexiau, Nadia Bouloufa-Maafa, Olivier Dulieu

J. Quant. Spectrosc. Rad. Transfer, 291, 108330 (2020)

DOI:10.1016/j.jqsrt.2022.108330

arxiv:10.48550/arXiv.2207.02484

Article supplementary experimental data

Attachments:

Ab_initio_PEC_Hund_A.dat	[ ]	16 Kb
Ab_initio_PEC_Hund_C.dat	[ ]	9 Kb
Experimental_energy_levels.dat	[ ]	70 Kb
MSO_1Pi_3Delta.dat	[ ]	3 Kb
MSO_1Pi_3Pi.dat	[ ]	3 Kb
MSO_3Delta_3Delta.dat	[ ]	3 Kb
MSO_3Pi_3Delta.dat	[ ]	3 Kb
MSO_3Sig_1Pi.dat	[ ]	3 Kb
MSO_3Sig_3Pi.dat	[ ]	3 Kb
TDM_atSig_3tPi.dat	[ ]	2 Kb
TDM_atSig_4tSig.dat	[ ]	2 Kb
TDM_XsSig_3sPi.dat	[ ]	2 Kb
TDM_XsSig_4sSig.dat	[ ]	2 Kb

Observation of D(2)¹Π~ (2)³Π~(2)³Σ⁺ states in KCs by polarisation labelling spectroscopy technique. Modelling of the D(2)¹Π~ (2)³Π₁ system

J. Szczepkowski, A. Grochola, P. Kowalczyk, W. Jastrzebski,

J. Quant. Spectrosc. Rad. Transfer, 248, 106984 (2020)

DOI : 10.1016/j.jqsrt.2020.106984

Article supplementary experimental data

Attachments:

Distribution_of_the_residua.pdf	[ ]	159 Kb
Supp_full_set_of_levels.txt	[ ]	236 Kb
Supp_lines_comp.txt	[ ]	134 Kb

Determination of the C(3)¹Σ⁺state potential energy curve in KCs molecule based on polarisation labelling spectroscopy data

J. Szczepkowski, A. Grochola, P. Kowalczyk, W. Jastrzebski, 

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 224, 117331 (2020)

DOI 10.1016/j.saa.2019.117331

Article supplementary experimental data

Attachments:

Suppl_KCs_CsS_Dunham.txt	[Dunham coefficient (in cm^-1)]	1 Kb
Suppl_KCs_CsS_enlevels.txt	[Experimental energy levels of the C(3)1Sigma+ state]	45 Kb
Suppl_KCs_CsS_Fig_Pert.pdf	[Positions of the locally perturbed energy levels ]	594 Kb
Suppl_KCs_CsS_Fig_RKR.pdf	[Comparison between the IPA and RKR PECs]	500 Kb
Suppl_KCs_CsS_IPApot.txt	[Experimental IPA curve of the C(3)1Sigma+ electronic state]	1 Kb
Suppl_KCs_CsS_RKR.txt	[RKR potential energy curve for the C(3)1Sigma+ state]	2 Kb

The spin-orbit coupling of the 6¹Σ⁺ and 4^3Π states in KCs: observation and deperturbation

J. Szczepkowski, A. Grochola, P. Kowalczyk, W. Jastrzebski, E. Pazyuk , A.V. Stolyarov, A. Pashov, 

J. Quant. Spectrosc. Rad. Transfer, 239, 106650 (2019)

DOI  10.1016/j.jqsrt.2019.106650

Article supplementary experimental data

Attachments:

Table I.txt	[The potential energy curves for the $6^1\Sigma^+$ and $4^3\Pi$ states in KCs]	1 Kb
Table II.txt	[The off-diagonal spin-orbit function]	0.7 Kb
Table III.txt	[A comparison between the experimental and the calculated term energies]	149 Kb

Spectroscopic study of the C(3)¹Σ⁺ ← X¹Σ⁺ and c(2)^3Σ⁺ ← X¹Σ⁺ transitions in KCs molecule

J. Szczepkowski, A. Grochola, P. Kowalczyk, W. Jastrzebski,  J. Quant. Spectrosc. Rad. Transfer 204 p.131-137 (2018)

DOI 10.1016/j.jqsrt.2017.09.013

Article supplementary experimental data

Attachments:

KCs_CsSigma_pot.txt	[Pointwise representation of the potential curve of the C(3)1Sigma+ state]	1 Kb
KCs_CsSigma_term.txt	[Experimental energy levels of the C(3)1Sigma+ state]	12 Kb
KCs_ctSigma_pot.txt	[Pointwise representation of the potential curve of the c(2)3Sigma+ state]	1 Kb
KCs_ctSigma_term.txt	[Experimental energy levels of the c(2)3Sigma+ state]	19 Kb

Polarisation labelling spectroscopy of the 5¹Π state in KCs molecule

J. Szczepkowski   Chem. Phys Lett. 638 p.78-81(2015)

DOI 10.1016/j.cplett.2015.08.037

Article supplementary experimental data

Attachments:

exp_dunham.txt	[The experimentally determined Dunham coefficient (in cm^-1) for the v'in[0,4] of the 5 ^1Pi state]	0.7 Kb
exp_energies_lev_KCs_5sPi.txt	[Experimental energies of (v', J') rovibrational levels KCs 5sPi]	30 Kb
exp_potential.txt	[The rotationless IPA potential energy curve for the 5 1PI state in KCs]	1 Kb
KCs_5sP.IPA	[Experimental potential curve data file IPA format]	1 Kb

Experimental investigation of the 6¹Σ⁺ 'shelf' state of KCs

J. Szczepkowski, A Grochola, W. Jastrzebski, P. Kowalczyk,  Chem. Phys. Lett. 614, 36-40 (2014)

DOI: 10.1016/j.cplett.2014.08.065

Article supplementary experimental data

Attachments:

KCs_6sS.ipa	[Experimental potential curve data file IPA format]	2 Kb
suppl_KCs_6Sigma.pdf	[Experimental energies of (v', J') rovibrational levels KCs (6) 1Sig]	88 Kb

Study of 4¹Π state in KCs molecule by polarisation labelling spectroscopy

J. Szczepkowski, A Grochola, W. Jastrzebski, P. Kowalczyk  Chem. Phys Lett. Vol. 576, p. 10–14, (2013)

DOI: 10.1016/j.cplett.2013.05.022

Article supplementary experimental data

Attachments:

exp_energies_lev_KCs_4Pi.txt	[Experimental energies of (v', J') rovibrational levels KCs 4Pi]	58 Kb
KCs_4sPI.ipa	[Experimental potential curve data file IPA format]	2 Kb

On the 4¹Σ⁺ state of KCs molecule

J. Szczepkowski, A Grochola, W Jastrzębski, P. Kowalczyk, J. Mol. Spectr. 276, 19-21 (2012)

DOI: 10.1016/j.jms.2012.06.004

Article supplementary experimental data

Attachments:

KCs_4S.ipa

[Experimental potential curve data file IPA format]

2 Kb